Neutron diffraction and in situ gas-loading investigations of functional MOFs for energy-relevant gas separations

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dc.contributor.authorDuyker, SGen_AU
dc.contributor.authorPeterson, VKen_AU
dc.contributor.authorOgilvie, SHen_AU
dc.contributor.authorTurner, DRen_AU
dc.contributor.authorHill, MRen_AU
dc.contributor.authorD'Alessandro, DMen_AU
dc.contributor.authorKepert, CJen_AU
dc.date.accessioned2021-09-23T02:12:45Zen_AU
dc.date.available2021-09-23T02:12:45Zen_AU
dc.date.issued2012-11-08en_AU
dc.date.statistics2021-09-22en_AU
dc.descriptionNot available online. Conference Handbook is held by ANSTO Library at DDC 539.758/9.en_AU
dc.description.abstractIntense research is currently directed towards realising metal-organic frameworks (MOFs) for industrially-applied gas separation and storage due to their unique structural properties, including: robustness; thermal and chemical stability; unprecedented internal surface area; and high void volume. A particular focus of current research is the development of MOFs for the separation of CO, from the other components of flue gas in fossil-fuelled power plants. The use of NPD to study gas adsorption in framework materials is a relatively new but growing field. Structural measurements, which show the arrangement of both the host and guest, allow derivation of the nature of the host-guest interaction, and the host's response to the guest. The capability to perform these measurements, with accurate gas dosing and temperature control, has recently been realised at ANSTO's Bragg Institute. Using these techniques, we have investigated the adsorption mechanisms of a number of gases in selected new and established MOFs that display impressive selectivity for specific gases. The location and orientation of industrially-relevant gases including D2, 02, CO2, and CD4, within their crystal structures provide insights into the modes of binding, which will help to tune the materials' performance and benefit the design and development process for the next generation of materials.en_AU
dc.identifier.citationDuyker, S. G., Peterson, V. K., Ogilvie, S. H., Turner, D. R., Hill, M. R., D'Alessandro, D. M. & Kepert, C. J. (2012). Neutron diffraction and in situ gas-loading investigations of functional MOFs for energy-relevant gas separations. Paper presented at the 10th AINSE-ANBUG Neutron Scattering Symposium (AANSS), Sydney, 7- 9 November 2012 (pp. 36)en_AU
dc.identifier.conferenceenddate9 November 2012en_AU
dc.identifier.conferencename10th AINSE-ANBUG Neutron Scattering Symposium (AANSS)en_AU
dc.identifier.conferenceplaceSydney, NSW, Australiaen_AU
dc.identifier.conferencestartdate7 November 2012en_AU
dc.identifier.pagination36en_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/11814en_AU
dc.language.isoenen_AU
dc.publisherAustralian Institute of Nuclear Science and Engineering (AINSE)en_AU
dc.subjectNeutron diffractionen_AU
dc.subjectGasesen_AU
dc.subjectMaterialsen_AU
dc.subjectFossil fuelsen_AU
dc.subjectCarbon dioxideen_AU
dc.subjectFlue gasen_AU
dc.subjectCrystal structureen_AU
dc.subjectAbsorptionen_AU
dc.titleNeutron diffraction and in situ gas-loading investigations of functional MOFs for energy-relevant gas separationsen_AU
dc.typeConference Presentationen_AU
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