Small angle neutron scattering on critical polymer clusters formed with tetra-armed prepolymers

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dc.contributor.authorLi, Xen_AU
dc.contributor.authorHirosawa, Ken_AU
dc.contributor.authorSakai, Ten_AU
dc.contributor.authorGilbert, EPen_AU
dc.contributor.authorShibayama, Men_AU
dc.date.accessioned2021-08-09T22:26:02Zen_AU
dc.date.available2021-08-09T22:26:02Zen_AU
dc.date.issued2017-07-12en_AU
dc.date.statistics2021-08-09en_AU
dc.description.abstractSol-gel transition is one of phenomena classified to percolation transition. Percolation has been extensively investigated in 1970s – 1990s both experimentally and theoretically. By tuning the concentrations and ratio of monomers and crosslinkers, one can synthesize various critical clusters on the verge of percolation. However, most of the previous studies only focused on one critical conditions (one monomer concentration and one crosslinker ratio). Recently, we succeeded in preparation of critical polymer clusters by cross-end-coupling multi-arm prepolymers, which shows less side-reactions and generates critical polymer clusters with good reproducibility. In this presentation, we revisit this old problem by using well-tuned polymer network clusters at various critical conditions, discuss the structure of critical polymer clusters, and demonstrate some applications.en_AU
dc.identifier.citationLi, X., Hirosawa, K., Sakai, T., Gilbert, E., & Shibayama, M. (2017). Small angle neutron scattering on critical polymer clusters formed with tetra-armed prepolymers. Paper presented at ICNS 2017 (International Conference on Neutron Scattering), Daejeon, South Korea, 9 to 13 July 2017. Retrieved from: http://www.icns2017.org/program.phpen_AU
dc.identifier.conferenceenddate13 July 2017en_AU
dc.identifier.conferencenameICNS 2017 (International Conference on Neutron Scattering)en_AU
dc.identifier.conferenceplaceDaejeon, South Koreaen_AU
dc.identifier.conferencestartdate9 July 2017en_AU
dc.identifier.urihttp://www.icns2017.org/program.phpen_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/11283en_AU
dc.language.isoenen_AU
dc.publisherInternational Conference on Neutron Scatteringen_AU
dc.subjectSol-gel processen_AU
dc.subjectMonomersen_AU
dc.subjectPolymersen_AU
dc.subjectIon pairsen_AU
dc.subjectFluidsen_AU
dc.subjectNeutron diffractionen_AU
dc.titleSmall angle neutron scattering on critical polymer clusters formed with tetra-armed prepolymersen_AU
dc.typeConference Abstracten_AU
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