Structure and dehydration of the pyrochlore system NaW2−yMoyO6+δ·nH2−zO between 10 and 675 K

The temperature dependence of the structure of the pyrochlore NaW2−yMoyO6+δ·nH2−zO has been investigated using a variety of diffraction and spectroscopic methods. The positions of OH−/H2O molecules in the structure have been determined. Increases in temperature induce small lattice parameter changes, which are thought to result from movement of the H2O molecules in the pyrochlore lattice. Crown Copyright © 2008 Published by Elsevier Ltd.

Keywords

X-ray diffraction, Spectroscopy, Temperature dependence, Dehydration, Pyrochlore, Crystal structure, Crystal lattices, Nuclear magnetic resonance

Citation

Thorogood, G. J., Kennedy, B. J., Luca, V., Blackford, M., van de Geest, S. K., Finnie, K. S., Hanna, J. V. & Pike, K. J. (2008). Structure and dehydration of the pyrochlore system NaW2−yMoyO6+δ·nH2−zO between 10 and 675 K. Journal of Physics and Chemistry of Solids, 69(7), 1632-1640. doi:10.1016/j.jpcs.2007.12.008

URI

https://doi.org/10.1016/j.jpcs.2007.12.008
https://apo.ansto.gov.au/dspace/handle/10238/13051

Collections

Journal Articles

Full item page

Structure and dehydration of the pyrochlore system NaW2−yMoyO6+δ·nH2−zO between 10 and 675 K

Files

Date

Authors

Journal Title

Journal ISSN

Volume Title

Publisher

Abstract

Description

Keywords

Citation

URI

Collections

Endorsement

Review

Supplemented By

Referenced By