Phase separation in the organic solid state: simultaneous synchrotron SAXS / DSC studies of unstable n-alkane blends

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dc.contributor.authorGilbert, EPen_AU
dc.contributor.authorNelson, Aen_AU
dc.contributor.authorSutton, Den_AU
dc.contributor.authorTerrill, Nen_AU
dc.contributor.authorMartin, Cen_AU
dc.contributor.authorLal, Jen_AU
dc.contributor.authorLang, EAen_AU
dc.date.accessioned2021-09-09T00:54:31Zen_AU
dc.date.available2021-09-09T00:54:31Zen_AU
dc.date.issued2005-01-31en_AU
dc.date.statistics2021-08-31en_AU
dc.description.abstractBlends of normal alkanes form lamellar structures, when quenched from the melt, in which the separation of the individual chains may be controlled by the chain-length difference, molar composition, isotopic substitution and confinement. We have performed simultaneous synchrotron small-angle X-ray scattering and differential scanning calorimetry studies on 2:1 C28H58:C36D74 mixtures as a function of cooling protocol. Their simultaneous collection enables the temperature-dependent nanostructural changes to be correlated with phase transitions. The data are further complemented by small-angle neutron scattering highlighting the separation of the individual chains via isotopic contrast and optical microscopy indicating changes occurring on the macroscopic scale.en_AU
dc.identifier.citationGilbert, E. P., Nelson, A., Sutton, D., Terrill, N., Martin, C., Lal, J. & Lang, E. (2005). Phase separation in the organic solid state: simultaneous synchrotron SAXS / DSC studies of unstable n-alkane blends. Paper presented to the 29th Condensed Matter and Materials Meeting, "Australian Institute of Physics Sixteenth Biennial Congress", Canberra, 2005, 31 January - 4 February 2005. Retrieved from: https://web.archive.org/web/20050615003041/http://aipcongress2005.anu.edu.au/pdf/AIPC_Handbook_V2.pdfen_AU
dc.identifier.conferenceenddate4 February 2005en_AU
dc.identifier.conferencename29th Condensed Matter and Materials Meeting, 'Australian Institute of Physics Sixteenth Biennial Congress'en_AU
dc.identifier.conferenceplaceCanberra, Australiaen_AU
dc.identifier.conferencestartdate31 January 2005en_AU
dc.identifier.isbn0-9598064-8-2en_AU
dc.identifier.uriURI:https://web.archive.org/web/20050615003041/http://aipcongress2005.anu.edu.au/pdf/AIPC_Handbook_V2.pdfen_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/11656en_AU
dc.language.isoenen_AU
dc.publisherAustralian Institute of Physicsen_AU
dc.subjectAcceleratorsen_AU
dc.subjectCoherent scatteringen_AU
dc.subjectCyclic acceleratorsen_AU
dc.subjectDiffractionen_AU
dc.subjectDispersionsen_AU
dc.subjectHydrocarbonsen_AU
dc.subjectMicroscopyen_AU
dc.subjectOrganic compoundsen_AU
dc.subjectScatteringen_AU
dc.titlePhase separation in the organic solid state: simultaneous synchrotron SAXS / DSC studies of unstable n-alkane blendsen_AU
dc.typeConference Abstracten_AU
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