Hydration as a trigger for new properties in inorganic materials

Simple item page
dc.contributor.authorDuyker, SGen_AU
dc.contributor.authorPeterson, VKen_AU
dc.contributor.authorKearley, GJen_AU
dc.contributor.authorStuder, AJen_AU
dc.contributor.authorKepert, CJen_AU
dc.contributor.authorHill, JAen_AU
dc.contributor.authorHoward, CJen_AU
dc.contributor.authorGoodwin, ALen_AU
dc.date.accessioned2021-10-26T21:13:29Zen_AU
dc.date.available2021-10-26T21:13:29Zen_AU
dc.date.issued2016-11-29en_AU
dc.date.statistics2021-10-11en_AU
dc.description.abstractThe humble water molecule binds to metal ions strongly enough that it can have a significant distortive influence on the coordination geometry, yet weakly enough that it can be readily removed, thus providing scope for reversible chemical switching between structural forms. When this principle is applied in 3D coordination frameworks, the unique topological constraints of the framework can lead to new behaviours. Examples from our work will be presented, including anomalous mechanical properties enabled by unsaturated coordination spheres,[1] and new kinds of symmetry breaking transformations triggered by (de)hydration[2] (see figure).en_AU
dc.identifier.citationDuyker, S. G., Peterson, V. K., Kearley, G. J., Studer, A. J., Kepert, C. J., Hill, J. A., Howard, C. J., & Goodwin, A. L. (2016). Hydration as a trigger for new properties in inorganic materials. Paper presented at 13th AINSE-ANBUG Neutron Scattering Symposium, Sydney, NSW, Australia, 29-30 November 2016.en_AU
dc.identifier.conferenceenddate30 November 2016en_AU
dc.identifier.conferencename13th AINSE-ANBUG Neutron Scattering Symposiumen_AU
dc.identifier.conferenceplaceSydney, NSW, Australiaen_AU
dc.identifier.conferencestartdate29 November 2016en_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/12092en_AU
dc.language.isoenen_AU
dc.publisherAustralian Institute of Nuclear Science and Engineeringen_AU
dc.subjectMetalsen_AU
dc.subjectGeometryen_AU
dc.subjectMechanical propertiesen_AU
dc.subjectSymmetry breakingen_AU
dc.subjectHydrationen_AU
dc.subjectDehydrationen_AU
dc.titleHydration as a trigger for new properties in inorganic materialsen_AU
dc.typeConference Abstracten_AU
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
Abstract_Handbook_v2(1).pdf
Size:
1.87 MB
Format:
Adobe Portable Document Format
Description:
Download
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.63 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Conference Publications