Orthogonal antiferromagnetism to canted ferromagnetism in CaCo3Ti4O12 quadruple perovskite driven by underlying kagome lattices
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Date
2022-08-01
Journal Title
Journal ISSN
Volume Title
Publisher
Springer Nature
Abstract
AA′3B4O12 quadruple perovskites, with magnetic A′ and non-magnetic B cations, are characterized by a wide range of complex magnetic structures. These are due to a variety of competing spin-exchange interactions up to the fourth nearest neighbours. Here, we synthesize and characterize the magnetic behaviour of the CaCo3Ti4O12 quadruple perovskite. We find that in the absence of an external magnetic field, the system undergoes antiferromagnetic ordering at 9.3 K. This magnetic structure consists of three interpenetrating mutually orthogonal magnetic sublattices. Under an applied magnetic field, this antiferromagnetic structure evolves into a canted ferromagnetic structure. In explaining these magnetic structures, as well as the seemingly unrelated magnetic structures found in other quadruple perovskites, we suggest a crucial role played by the underlying kagome lattices in these systems. All observed magnetic structures of these materials represent indeed one of the three possible ways to reduce spin frustration in the A′ site kagome layers. More specifically, our survey of the magnetic structures observed for quadruple perovskites AA′3B4O12 reveals the following three ways to reduce spin frustration, namely to make each layer ferromagnetic, to adopt a compromise 120° spin arrangement in each layer, or to have a magnetic structure with a vanishing sum of all second nearest-neighbour spin exchanges. © The Authors - Open Access CC BY 4.0
Description
Keywords
Antiferromagnetism, Perovskites, Cations, Calcium, Cobalt, Titanium, Magnetic fields, Spin, Crystal lattices
Citation
Amano Patino, M., Denis Romero, F., Koo, H.-J., Avdeev, M., Injac, S. D. A., Goto, M., Whangbo, M.-H., & Shimakawa, Y. (2022). Orthogonal antiferromagnetism to canted ferromagnetism in CaCo3Ti4O12 quadruple perovskite driven by underlying kagome lattices. Communications Materials, 3(1), 51. doi:10.1038/s43246-022-00274-y