Insights into selective gas sorbent functionality gained by using time-resolved neutron diffraction

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dc.contributor.authorAuckett, JEen_AU
dc.contributor.authorDuyker, SGen_AU
dc.contributor.authorTurner, DRen_AU
dc.contributor.authorBatten, SRen_AU
dc.contributor.authorPeterson, VKen_AU
dc.date.accessioned2021-08-25T00:00:28Zen_AU
dc.date.available2021-08-25T00:00:28Zen_AU
dc.date.issued2018-05-05en_AU
dc.descriptionSpecial Issue: Leone Spiccia Memorial Issueen_AU
dc.description.abstractAn understanding of the atomic-scale interactions between gas sorbent materials and their molecular guests is essential for the identification of the origins of desirable function and the rational optimization of performance. However, characterizations performed on equilibrated sorbent–guest systems may not accurately represent their behavior under dynamic operating conditions. The emergence of fast (minute-scale) neutron powder diffraction coupled with direct, real-time quantification of gas uptake opens up new possibilities for obtaining knowledge about concentration-dependent effects of guest loading upon function-critical features of sorbent materials, including atomic structure, diffusion pathways, and thermal expansion of the sorbent framework. This article presents a detailed investigation of the ultramicroporous metal–organic framework [Cu3(cdm)4] as a case study to demonstrate the variety of insights into sorbent performance that can be obtained from real-time characterizations using neutron diffraction. © 2018 Wiley-VCH Verlag GmbH & Coen_AU
dc.identifier.citationAuckett, J. E., Duyker, S. G., Turner, D. R., Batten, S. R., & Peterson, V. K. (2018). Insights into selective gas sorbent functionality gained by using time‐resolved neutron diffraction. ChemPlusChem, 83(7), 669-675. doi:10.1002/cplu.201800210en_AU
dc.identifier.issn2192-6506en_AU
dc.identifier.issue7en_AU
dc.identifier.journaltitleChemPlusChemen_AU
dc.identifier.pagination669-675en_AU
dc.identifier.urihttps://doi.org/10.1002/cplu.201800210en_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/11479en_AU
dc.identifier.volume83en_AU
dc.language.isoenen_AU
dc.publisherJohn Wiley & Sons, Incen_AU
dc.subjectGasesen_AU
dc.subjectCarbon dioxideen_AU
dc.subjectThermal expansionen_AU
dc.subjectNeutron diffractionen_AU
dc.subjectSorptionen_AU
dc.subjectDiffusionen_AU
dc.titleInsights into selective gas sorbent functionality gained by using time-resolved neutron diffractionen_AU
dc.typeJournal Articleen_AU
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