dc.contributor.author	Söhnel, T	en_AU
dc.contributor.author	Rey, E	en_AU
dc.contributor.author	Ling, CD	en_AU
dc.contributor.author	Avdeev, M	en_AU
dc.contributor.author	Johannessen, B	en_AU
dc.contributor.author	Wallwork, KS	en_AU
dc.contributor.author	Kremer, RK	en_AU
dc.contributor.author	Whangbo, MH	en_AU
dc.date.accessioned	2021-10-14T00:03:12Z	en_AU
dc.date.available	2021-10-14T00:03:12Z	en_AU
dc.date.issued	2011-02-04	en_AU
dc.date.statistics	2021-09-07	en_AU
dc.description.abstract	One very interesting compound in the system Cu/Sb/O is the mixed-valent Cu5SbO6 = (Cu1+(Cu2+ 2/3Sb5+ 1/3)O2) which is crystallising in the high temperature modification as a modified Delafossite structure type. Compounds like Delafossite, CuFeO2, is one of the few groups of compounds showing the rare property of multiferroic behaviour. In Cu5SbO6 the magnetically active brucite-like CuO2 layer is diluted in an ordered fashion with nonmagnetic Sb5+. Cu5SbO6 also shows a phase transition, which exhibits a rather complicated behaviour. It depends on the temperature and the reaction conditions (reactants for preparation, pressure, open or closed system). High resolution Synchrotron and neutron powder diffraction measurements could clearly distinguish between the high temperature and the low temperature modification and reveal an ordering (HT-modification) / disordering (LT-modification) effect of the Sb5+ and Cu2+ ions in the brucite-like layers. The LT-modification can also be assigned to what had wrongly been described in the literature as Cu4.5SbO5. XANES Cu-K edge measurements and NPD measurements should clarify a potential oxidation of the Cu1+ to Cu2+ and a connected additional inclusion of oxygen in the structure. According to magnetic measurements and DFT calculations the magnetic structure in Cu5SbO6 can be described with a short range ferromagnetic-antiferromagnetic interaction model of the (Cu2+) pairs in the (Cu2+ 2/3Sb5+ 1/3)O2 layers with a super-exchange via the nonmagnetic Sb5+ atoms. The systematic replacement of the non-magnetic Sb5+ with magnetically active M5+ ions should change the magnetic properties dramatically and could lead to an long range ordering in the system. First results of Mn and Mo doping will also be presented.	en_AU
dc.identifier.citation	Söhnel, T., Rey, E., Ling, C., Avdeev, M., Johannessen, B., Wallwork, K., Kremer, R., & Whangbo, M.-H. (2011). Cu5SbO6 – synchrotron, neutron diffraction studies and magnetic properties. Paper presented to the Australian and New Zealand Institutes of Physics 35th Annual Condensed Matter and Materials Meeting, Charles Sturt University, Wagga Wagga, NSW, 2nd - 4th February, 2011. Retrieved from: https://physics.org.au/wp-content/uploads/cmm/2011/	en_AU
dc.identifier.conferenceenddate	4 February 2011	en_AU
dc.identifier.conferencename	Australian and New Zealand Institutes of Physics 35th Annual Condensed Matter and Materials Meeting	en_AU
dc.identifier.conferenceplace	Wagga Wagga, NSW	en_AU
dc.identifier.conferencestartdate	2 February 2011	en_AU
dc.identifier.isbn	978-0-646-55969-8	en_AU
dc.identifier.uri	https://physics.org.au/wp-content/uploads/cmm/2011/	en_AU
dc.identifier.uri	https://apo.ansto.gov.au/dspace/handle/10238/11953	en_AU
dc.language.iso	en	en_AU
dc.publisher	Australian Institute of Physics	en_AU
dc.subject	Copper	en_AU
dc.subject	Antimony	en_AU
dc.subject	Oxygen	en_AU
dc.subject	Neutron diffraction	en_AU
dc.subject	Magnetic properties	en_AU
dc.subject	Temperature range 0400-1000 K	en_AU
dc.subject	Iron	en_AU
dc.subject	Temperature range 0065-0273 K	en_AU
dc.subject	Manganese	en_AU
dc.title	Cu5SbO6 – synchrotron, neutron diffraction studies and magnetic properties	en_AU
dc.type	Conference Abstract	en_AU

Cu5SbO6 – synchrotron, neutron diffraction studies and magnetic properties

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