A study of di(amino)stibines with terminal Sb( iii ) hydrogen-ligands by X-ray- and neutron-diffraction

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dc.contributor.authorSchwamm, RJen_AU
dc.contributor.authorEdwards, AJen_AU
dc.contributor.authorFitchett, CMen_AU
dc.contributor.authorColes, MPen_AU
dc.date.accessioned2025-03-07T03:45:20Zen_AU
dc.date.available2025-03-07T03:45:20Zen_AU
dc.date.issued2019-01-31en_AU
dc.date.statistics2025-02-26en_AU
dc.description.abstractThe bis(amidodimethyl)disiloxane ligands [O{SiMe2NR}2]2− (R = 2,6-Me2C6H3 (Ar′) and 2,6-iPr2C6H3 (Ar), abbreviated [NONR]2−, are a stable support for Sb(III) complexes of general formula Sb(NONR)X (X = Cl, H). The compounds are monomeric in the solid-state, with bidentate N,N′-coordination of the [NONR]2− and terminal chloride/hydrogen-ligands. Sb(NONAr′)H was analyzed by single-crystal neutron diffraction, giving the first accurate parameters for the Sb–H bond to an antimony(III) centre. © Royal Society of Chemistry 2025.en_AU
dc.format.mediumPrinten_AU
dc.identifier.citationSchwamm, R. J., Edwards, A. J., Fitchett, C. M., & Coles, M. P. (2019). A study of di(amino)stibines with terminal Sb(iii) hydrogen-ligands by X-ray- and neutron-diffraction. Dalton Transactions, 48(9), 2953-2958. doi:10.1039/C8DT05113Een_AU
dc.identifier.issn1477-9226en_AU
dc.identifier.issn1477-9234en_AU
dc.identifier.issue9en_AU
dc.identifier.journaltitleDalton Transactionsen_AU
dc.identifier.pagination2953-2958en_AU
dc.identifier.urihttps://doi.org/10.1039/c8dt05113een_AU
dc.identifier.urihttps://apo.ansto.gov.au/handle/10238/16032en_AU
dc.identifier.volume48en_AU
dc.languageEnglishen_AU
dc.language.isoenen_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.subjectNeutron diffractionen_AU
dc.subjectHydrogenen_AU
dc.subjectSiliconen_AU
dc.subjectAntimonyen_AU
dc.subjectCrystalsen_AU
dc.subjectLigandsen_AU
dc.subjectChloridesen_AU
dc.subjectNeutron diffractionen_AU
dc.subjectChemical bondsen_AU
dc.subjectSynthesisen_AU
dc.titleA study of di(amino)stibines with terminal Sb( iii ) hydrogen-ligands by X-ray- and neutron-diffractionen_AU
dc.typeJournal Articleen_AU
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