Biphasic P2/O3-Na2/3Li0.18Mn0.8Fe0.2O2: a structural investigation

Simple item page
dc.contributor.authorStansby, JHen_AU
dc.contributor.authorAvdeev, Men_AU
dc.contributor.authorBrand, HEAen_AU
dc.contributor.authorGonzalo, Een_AU
dc.contributor.authorDrewett, NEen_AU
dc.contributor.authorOrtiz-Vitoriano, Nen_AU
dc.contributor.authorSharma, Nen_AU
dc.contributor.authorRojo, Ten_AU
dc.date.accessioned2021-09-07T02:12:11Zen_AU
dc.date.available2021-09-07T02:12:11Zen_AU
dc.date.issued2020-12-22en_AU
dc.date.statistics2021-09-07en_AU
dc.description.abstractThe P2/O3 layered oxide system is thought to benefit from a synergistic enhancement, resulting from the presence of both phases, which makes it a promising cathode material for Na-ion battery applications. Here, biphasic P2/O3-Na2/3Li0.18Mn0.8Fe0.2O2 is investigated via a combination of neutron and X-ray scattering techniques. Neutron diffraction data indicates that the O3 alkali metal site is fully occupied by Li. Real time operando X-ray diffraction data shows the structural evolution of the composite electrode – at the charged state there is no evidence of O2, OP4 or Z phases. The results presented herein provide new insight into site preference of Li in biphasic materials and highlights the value of utilizing multiple phases to achieve high performance layered cathode materials for sodium battery applications.© The Royal Society of Chemistry 2021en_AU
dc.identifier.citationStansby, J. H., Avdeev, M., Brand, H. E. A., Gonzalo, E., Drewett, N. E., Ortiz-Vitoriano, N., Sharma, N., & Rojo, T. (2021). Biphasic P2/O3-Na2/3Li0.18Mn0.8Fe0.2O2: a structural investigation. Dalton Transactions, 50(4), 1357-1365. doi:10.1039/D0DT03351Ken_AU
dc.identifier.issn1477-9234en_AU
dc.identifier.issue4en_AU
dc.identifier.journaltitleDalton Transactionsen_AU
dc.identifier.pagination1357-1365en_AU
dc.identifier.urihttps://doi.org/10.1039/D0DT03351Ken_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/11612en_AU
dc.identifier.volume50en_AU
dc.language.isoenen_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.subjectOxidesen_AU
dc.subjectCathodesen_AU
dc.subjectX-ray diffractionen_AU
dc.subjectNeutron diffractionen_AU
dc.subjectElectric batteriesen_AU
dc.subjectSodium ionsen_AU
dc.titleBiphasic P2/O3-Na2/3Li0.18Mn0.8Fe0.2O2: a structural investigationen_AU
dc.typeJournal Articleen_AU
Files
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.63 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Journal Articles