The application of neutron reflectometry and atomic force microscopy in the study of corrosion inhibitor films

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Date
2006-11-15
Journal Title
Journal ISSN
Volume Title
Publisher
Elsevier B. V.
Abstract
Corrosion inhibitor molecules function by adsorbing to a steel surface and thus prevent oxidation of the metal. The interfacial structures formed by a range of corrosion inhibitor molecules have been investigated by in situ measurements based on atomic force microscopy and neutron reflectometry. Inhibitors investigated include molecules cetyl pyridinium chloride (CPC), dodecyl pyridinium chloride (DPC), 1-hydroxyethyl-2-oleic imidazoline (OHEI) and cetyl dimethyl benzyl ammonium chloride (CDMBAC). This has shown that the inhibitor molecules adsorb onto a surface in micellar structures. Corrosion measurements confirmed that maximum inhibition efficiency coincides with the solution critical micelle concentration. Copyright © 2006 Elsevier B.V.
Description
Physical copy held by ANSTO Library at DDC 539.7213/3. Part I
Keywords
Alloys, Ammonium compounds, Ammonium halides, Baryons, Chlorides, Chlorine compounds, Fermions, Hadrons, Halogen compounds, Iron base alloys, Atomic force microscopy, Nucleons, Neutron reflectors, Corrosion, Films
Citation
John, D., Blom, A., Bailey, S., Nelson, A., Schulz, J., De Marco, R., & Kinsella, B. (2006). The application of neutron reflectometry and atomic force microscopy in the study of corrosion inhibitor films. Paper presented at the Eighth International Conference on Neutron Scattering (ICNS 2005), "Neutrons for structure and dynamics - a new era", Sydney, Australia, 27 November to 2 December 2005. In Campbell, S. J., Cadogan, J. M., Furusaka, M., Hauser, N., & James, M. (Eds), Physica B: Condensed Matter, 385-386(Part 2), 924-926. doi:10.1016/j.physb.2006.05.213