Neutron powder diffraction study of the nuclear and magnetic structures of LaMn1-xCrxO3.00 (x=0.05, and 0.15)

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dc.contributor.authorMorales, Len_AU
dc.contributor.authorCaneiro, Aen_AU
dc.contributor.authorJames, Men_AU
dc.date.accessioned2022-12-14T06:15:59Zen_AU
dc.date.available2022-12-14T06:15:59Zen_AU
dc.date.issued2006-11-15en_AU
dc.date.statistics2022-05-19en_AU
dc.descriptionPhysical copy held by ANSTO Library at DDC 539.7213/3. Part Ien_AU
dc.description.abstractA comparative study of the nuclear and magnetic structures of LaMn1-xCrxO3.00 perovskite (x=0.05, and 0.15) is reported. Cr3+ is isoelectronic with Mn4+(3d3) and is also a non-Jahn-Teller ion. Both magnetic ions increase the hole (empty eg levels) concentration and decrease the Jahn-Teller distortion. To characterize the interaction established between Mn3+ and Cr3+ and the effect of Cr3+ on the magnetic structure, samples without Mn4+ were synthesized. X-ray powder diffraction, at room temperature, reveals the existence of single phase materials with orthorhombic symmetry (Pnma) for all the studied samples. Magnetic data shows an increase of the FM interaction with Cr content. Magnetic phases change from A-type antiferromagnetic order to a system with magnetic clusters through a spin-glass-like phase. In order to fully understand the magnetic phase diagram, neutron powder diffraction was carried out. Both, nuclear and magnetic structures are studied as a function of temperature and Cr content. These results reveal the presence of more than one magnetic phase and a clear change of the spin orientation with temperature and Cr content. The mixture of magnetization and neutron powder diffraction data allow us to describe the role of the Cr3+ on the magnetic properties. © 2006 Elsevier B.V.en_AU
dc.identifier.citationMorales, L., Caneiro, A., & James, M. (2006). Neutron powder diffraction study of the nuclear and magnetic structures of LaMn1-xCrxO3.00 (x=0.05, and 0.15). Paper presented at the Eighth International Conference on Neutron Scattering (ICNS 2005), "Neutrons for structure and dynamics - a new era", Sydney, Australia, 27 November to 2 December 2005. In Campbell, S. J., Cadogan, J. M., Furusaka, M., Hauser, N., & James, M. (Eds), Physica B: Condensed Matter, 385-386(Part 1), 415-417. doi:10.1016/j.physb.2006.05.235en_AU
dc.identifier.conferenceenddate2 December 2005en_AU
dc.identifier.conferencenameEighth International Conference on Neutron Scattering ICNS 2005: 'Neutrons for structure and dynamics - a new eraen_AU
dc.identifier.conferenceplaceSydney, Australiaen_AU
dc.identifier.conferencestartdate27 November 2005en_AU
dc.identifier.editorsCampbell, S. J., Cadogan, J. M., Furusaka, M., Hauser, N., & James, M.en_AU
dc.identifier.issn0921-4526en_AU
dc.identifier.issuePart 1en_AU
dc.identifier.journaltitlePhysica B: Condensed Matteren_AU
dc.identifier.pagination415-417en_AU
dc.identifier.urihttps://doi.org/10.1016/j.physb.2006.05.235en_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/14179en_AU
dc.identifier.volume385-386en_AU
dc.language.isoenen_AU
dc.publisherElsevier B. V.en_AU
dc.subjectCharged particlesen_AU
dc.subjectCrystal structureen_AU
dc.subjectX-ray diffractionen_AU
dc.subjectInformationen_AU
dc.subjectIonsen_AU
dc.subjectMaterialsen_AU
dc.subjectMineralsen_AU
dc.subjectSpin orientationen_AU
dc.subjectOxygen compoundsen_AU
dc.subjectPerovskitesen_AU
dc.subjectRare earth compoundsen_AU
dc.subjectScatteringen_AU
dc.subjectTransition element compoundsen_AU
dc.subjectMagnetizationen_AU
dc.titleNeutron powder diffraction study of the nuclear and magnetic structures of LaMn1-xCrxO3.00 (x=0.05, and 0.15)en_AU
dc.typeConference Paperen_AU
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