Magnetic properties of Ln2CoGe4O12 and LnBCoGe4O12 (Ln = Gd, Tb, Dy, Ho, Er; B = Sc, Lu)

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dc.contributor.authorXu, Den_AU
dc.contributor.authorAvdeev, Men_AU
dc.contributor.authorBattle, PDen_AU
dc.contributor.authorRyan, DHen_AU
dc.date.accessioned2021-06-28T21:49:22Zen_AU
dc.date.available2021-06-28T21:49:22Zen_AU
dc.date.issued2017-11-03en_AU
dc.date.statistics2021-06-17en_AU
dc.description.abstractPolycrystalline samples of Ln2CoGe4O12 (Ln = Gd, Tb, Dy, Ho or Er) and LnBCoGe4O12 (B = Sc or Lu) have been prepared and characterised by a combination of magnetometry, 155Gd Mössbauer spectroscopy and, in the case of Tb2CoGe4O12 and TbScCoGe4O12, neutron diffraction. The holmium- and erbium-containing compositions remain paramagnetic down to 2 K, those containing dysprosium behave as spin glasses and the terbium and gadolinium-containing compounds show long-range magnetic order with transition temperatures below 4 K in all cases. The data can be rationalized qualitatively in terms of the interplay between magnetic anisotropy and crystal field effects. © Royal Society of Chemistry 2021en_AU
dc.identifier.citationXu, D., Avdeev, M., Battle, P. D., & Ryan, D. H. (2017). Magnetic properties of Ln2CoGe4O12 and LnBCoGe4O12 (Ln = Gd, Tb, Dy, Ho, Er; B = Sc, Lu). Dalton Transactions, 46(45), 15778-15788. doi:10.1039/C7DT03649Cen_AU
dc.identifier.issn1477-9234en_AU
dc.identifier.issue45en_AU
dc.identifier.journaltitleDalton Transactionsen_AU
dc.identifier.pagination15778-15788en_AU
dc.identifier.urihttps://doi.org/10.1039/C7DT03649Cen_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/10923en_AU
dc.identifier.volume46en_AU
dc.language.isoenen_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.subjectPolycrystalsen_AU
dc.subjectMagnetometersen_AU
dc.subjectSpectroscopyen_AU
dc.subjectNeutron diffractionen_AU
dc.subjectDysprosiumen_AU
dc.subjectTerbiumen_AU
dc.subjectGadoliniumen_AU
dc.subjectAnisotropyen_AU
dc.subjectCrystal fielden_AU
dc.titleMagnetic properties of Ln2CoGe4O12 and LnBCoGe4O12 (Ln = Gd, Tb, Dy, Ho, Er; B = Sc, Lu)en_AU
dc.typeJournal Articleen_AU
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