Phase separation in the organic solid state: the influence of quenching protocol in unstable n-alkane blends

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dc.contributor.authorGilbert, EPen_AU
dc.contributor.authorNelson, ARJen_AU
dc.contributor.authorSutton, Den_AU
dc.contributor.authorTerrill, Nen_AU
dc.contributor.authorMartin, Cen_AU
dc.contributor.authorLal, Jen_AU
dc.contributor.authorLang, Een_AU
dc.date.accessioned2025-03-20T23:49:12Zen_AU
dc.date.available2025-03-20T23:49:12Zen_AU
dc.date.issued2005-08-31en_AU
dc.description.abstractBlends of normal alkanes form lamellar structures, when quenched from the melt, in which the separation of the individual chains may be controlled by the chain-length mismatch, molar composition, isotopic substitution and confinement. 2:1 C28H58:C36D74 mixtures have been investigated after subjection to a cooling rate varying over three orders of magnitude and intermediate annealing prior to reaching ambient. Quenching at 100°C/min yields similar behaviour to intermediate annealing between the pure components' melting points. Slow cooling at 0.1°C/min generates significantly greater ordering and behaviour comparable to that obtained from annealing mid-way between the mixing transition and the C28H 58 melting point. © 20u25Informa UK Limiteden_AU
dc.identifier.citationGilbert, E. P., Nelson, A., Sutton, D., Terrill, N., Martin, C., Lal, J., & Lang, E. (2005). Phase separation in the organic solid state: the influence of quenching protocol in unstable n-alkane blends. Molecular Crystals and Liquid Crystals, 440(1), 93–105. doi:10.1080/15421400590957882en_AU
dc.identifier.issn1542-1406en_AU
dc.identifier.issn1563-5287en_AU
dc.identifier.issue1en_AU
dc.identifier.journaltitleMolecular Crystals and Liquid Crystalsen_AU
dc.identifier.pagination93-105en_AU
dc.identifier.urihttps://doi.org/10.1080/15421400590957882en_AU
dc.identifier.urihttps://apo.ansto.gov.au/handle/10238/16080en_AU
dc.identifier.volume440en_AU
dc.languageEnglishen_AU
dc.language.isoenen_AU
dc.publisherTaylor & Francisen_AU
dc.subjectSeparation processesen_AU
dc.subjectSolid state physicsen_AU
dc.subjectQuenchingen_AU
dc.subjectAlkanesen_AU
dc.subjectLamellaeen_AU
dc.subjectAnnealingen_AU
dc.subjectMelting pointsen_AU
dc.subjectSmall angle scatteringen_AU
dc.titlePhase separation in the organic solid state: the influence of quenching protocol in unstable n-alkane blendsen_AU
dc.typeJournal Articleen_AU
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