Colossal zero-field-cooled exchange bias via tuning compensated ferrimagnetic in kagome metals

Simple item page
dc.contributor.authorZhou, Hen_AU
dc.contributor.authorCao, Yen_AU
dc.contributor.authorKhmelevskyi, Sen_AU
dc.contributor.authorZhang, Qen_AU
dc.contributor.authorHu, Sen_AU
dc.contributor.authorAvdeev, Men_AU
dc.contributor.authorWang, CWen_AU
dc.contributor.authorZhou, Ren_AU
dc.contributor.authorYu, Cen_AU
dc.contributor.authorChen, Xen_AU
dc.contributor.authorLi, Qen_AU
dc.contributor.authorMiao, Jen_AU
dc.contributor.authorLi, Qen_AU
dc.contributor.authorLin, Ken_AU
dc.contributor.authorXing, XRen_AU
dc.date.accessioned2024-12-19T03:09:33Zen_AU
dc.date.available2024-12-19T03:09:33Zen_AU
dc.date.issued2024-07-22en_AU
dc.date.statistics2024-11-15en_AU
dc.description.abstractExchange bias (EB) is a crucial property with widespread applications but particularly occurs by complex interfacial magnetic interactions after field cooling. To date, intrinsic zero-field-cooled EB (ZEB) has only emerged in a few bulk frustrated systems and their magnitudes remain small yet. Here, enabled by high temperature synthesis, we uncover a colossal ZEB field of 4.95 kOe via tuning compensated ferrimagnetism in a family of kagome metals, which is almost twice the magnitude of known materials. Atomic-scale structure, spin dynamics, and magnetic theory revealed that these compensated ferrimagnets originate from significant antiferromagnetic exchange interactions embedded in the holmium-iron ferrimagnetic matrix due to supersaturated preferential manganese doping. A random antiferromagnetic order of manganese sublattice sandwiched between ferromagnetic iron kagome bilayers accounts for such unconventional pinning. The outcome of the present study outlines disorder-induced giant bulk ZEB and coercivity in layered frustrated systems. © 2024 American Chemical Society.en_AU
dc.description.sponsorshipThis research was supported by National Key R&D Program of China (2020YFA0406202), National Natural Science Foundation of China (22275015, 22090042), Fundamental Research Funds for the Central Universities, China (FRF-EYIT-23-03, FRF-IDRY-23-020). Neutron diffraction experiments were carried out in Australian Nuclear Science and Technology Organisation (ANSTO). The synchrotron radiation experiments were conducted at the BL44B2 of SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute (JASRI) (Proposal No.2023B1113). The authors acknowledge Dr. Jun Luo and Dr. Ransheng Jia for assisting in collecting the temperature dependence of Nuclear Magnetic Resonance (NMR) data using the NMR spectrometer of Synergetic Extreme Condition User Facility (SECUF).en_AU
dc.format.mediumPrint-Electronicen_AU
dc.identifier.citationZhou, H., Cao, Y., Khmelevskyi, S., Zhang, Q., Hu, S., Avdeev, M., Wang, C.-W., Zhou, R., Yu, C., Chen, X., Li, Q., Miao, J., Li, Q., Lin, K., & Xing, X. (2024). Colossal zero-field-cooled exchange bias via tuning compensated ferrimagnetic in kagome metals. Journal of the American Chemical Society, 146(30), 20770-20777. doi.:10.1021/jacs.4c04173en_AU
dc.identifier.issn0002-7863en_AU
dc.identifier.issn1520-5126en_AU
dc.identifier.issue30en_AU
dc.identifier.journaltitleJournal of the American Chemical Societyen_AU
dc.identifier.urihttps://doi.org/10.1021/jacs.4c04173en_AU
dc.identifier.urihttps://apo.ansto.gov.au/handle/10238/15834en_AU
dc.identifier.volume146en_AU
dc.languageEnglishen_AU
dc.language.isoenen_AU
dc.publisherAmerican Chemical Societyen_AU
dc.subjectFerrimagnetismen_AU
dc.subjectMetalsen_AU
dc.subjectMagnetismen_AU
dc.subjectCoolingen_AU
dc.subjectTemperature rangeen_AU
dc.subjectSynthesisen_AU
dc.subjectHolmiumen_AU
dc.subjectIronen_AU
dc.subjectAntiferromagnetismen_AU
dc.titleColossal zero-field-cooled exchange bias via tuning compensated ferrimagnetic in kagome metalsen_AU
dc.typeJournal Articleen_AU
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
ja4c04173_si_001.pdf
Size:
3 MB
Format:
Adobe Portable Document Format
Description:
Download
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.66 KB
Format:
Plain Text
Description:
Download
Collections
Journal Articles