Growth of LiCoO2 single crystals by the TSFZ method

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dc.contributor.authorNakamura, Sen_AU
dc.contributor.authorMaljuk, Aen_AU
dc.contributor.authorMaruyama, Yen_AU
dc.contributor.authorNagao, Men_AU
dc.contributor.authorWatauchi, Sen_AU
dc.contributor.authorHayashi, Ten_AU
dc.contributor.authorAnzai, Yen_AU
dc.contributor.authorFurukawa, Yen_AU
dc.contributor.authorLing, CDen_AU
dc.contributor.authorDeng, Gen_AU
dc.contributor.authorAvdeev, Men_AU
dc.contributor.authorBüchner, Ben_AU
dc.contributor.authorTanaka, Ien_AU
dc.date.accessioned2021-06-03T02:26:53Zen_AU
dc.date.available2021-06-03T02:26:53Zen_AU
dc.date.issued2018-11-08en_AU
dc.date.statistics2021-05-31en_AU
dc.description.abstractWe have grown LiCoO2 single crystals by the traveling solvent floating zone (TSFZ) growth with Li-rich solvent, having observed the incongruent melting behavior of LiCoO2 between 1100 and 1300 °C. The optimum growth conditions in terms of atmosphere and solvent composition were determined to be Ar flow and an atomic ratio Li/Co 85:15, respectively. The crystals grown using a conventional-mirror-type furnace contained periodic inclusions of a Co–O phase due to the influence of Co–O phase segregation on the stability of the molten zone during growth. By using a tilted-mirror FZ furnace, inclusion-free LiCoO2 crystals of about 5 mm in diameter and 70 mm long were obtained at a tilting angle θ = 10°. The grown crystals were confirmed to be single-domain by neutron Laue diffraction. © 2018 American Chemical Societyen_AU
dc.identifier.citationNakamura, S., Maljuk, A., Maruyama, Y., Nagao, M., Watauchi, S., Hayashi, T., Anzai, Y., Furukawa, Y., Ling, C. D., Deng, G., Avdeev, M., Büchner, B., & Tanaka, I. (2019). Growth of LiCoO2 single crystals by the TSFZ method. Crystal Growth & Design, 19(1), 415–420. doi:10.1021/acs.cgd.8b01503en_AU
dc.identifier.issn1528-7505en_AU
dc.identifier.issue1en_AU
dc.identifier.journaltitleCrystal Growth & Designen_AU
dc.identifier.pagination415-420en_AU
dc.identifier.urihttps://doi.org/10.1021/acs.cgd.8b01503en_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/10807en_AU
dc.identifier.volume19en_AU
dc.language.isoenen_AU
dc.publisherAmerican Chemical Societyen_AU
dc.subjectCrystalsen_AU
dc.subjectCrystallizationen_AU
dc.subjectCrystal structureen_AU
dc.subjectEvaporationen_AU
dc.subjectSolventsen_AU
dc.subjectLaue methoden_AU
dc.subjectNeutron diffractionen_AU
dc.titleGrowth of LiCoO2 single crystals by the TSFZ methoden_AU
dc.typeJournal Articleen_AU
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