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Title: Effective Am(III)/Eu(III) separations using 2,6-bis(1,2,4-triazin-3-yl)pyridine (BTP) functionalised titania particles and hierarchically porous beads
Authors: Veliscek-Carolan, J
Jolliffe, KA
Hanley, TL
Keywords: Hybridization
Porous materials
Solvent extraction
Nuclear fuels
Purex process
Issue Date: 12-Jun-2015
Publisher: Royal Society of Chemistry
Citation: Veliscek-Carolan, J., Jolliffe, K. A., & Hanley, T. L. (2015). Effective Am (III)/Eu (III) separations using 2, 6-bis (1, 2, 4-triazin-3-yl) pyridine (BTP) functionalised titania particles and hierarchically porous beads. Chemical Communications, 51(57), 11433-11436. doi.:10.1039/C5CC03957F
Abstract: Hybrid materials which selectively extract Am(III) over Eu(III) from 0.01 M nitric acid solutions with fast kinetics and separation factors up to 160 have been synthesised. The materials consist of titania functionalised with a modified organic 2,6-bis(1,2,4-triazin-3-yl)pyridine (BTP) derivative. Both particles and hierarchically porous beads have been prepared and provide advantages over conventional solvent extraction separations. © 2015 The Royal Society of Chemistry
Gov't Doc #: 8891
URI: htts://
ISSN: 1364-548X
Appears in Collections:Journal Articles

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