Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/9101
Title: Dinuclear complexes of europium(III) and gadolinium(III) ions with a julolidine–quinoline-based tridentate ligand
Authors: Fanna, DJ
Zhang, Y
Salih, A
Reynolds, JK
Li, F
Keywords: Quinolines
Europium
Gadolinium
Ligands
X-ray diffraction
Raman spectroscopy
Electronic structure
Absorption
Emission spectroscopy
Scanning electron microscopy
Issue Date: 13-Jun-2016
Publisher: Taylor and Francis Online
Citation: Fanna, D. J., Zhang, Y., Salih, A., Reynolds, J. K., & Li, F. (2016). Dinuclear complexes of europium (III) and gadolinium (III) ions with a julolidine–quinoline-based tridentate ligand. Journal of Coordination Chemistry, 69(11-13), 1883-1892. doi:10.1080/00958972.2016.1194403
Abstract: The reaction of europium(III) or gadolinium(III) acetates with a Schiff base ligand {HL (C22H21N3O) = ((E)-9-((quinolin-8-ylimino)methyl)-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinolin-8-ol)} in methanol affords two dinuclear complexes which have been characterized by powder X-ray diffraction, Raman spectroscopy, scanning electron microscope–electron dispersive spectroscopy, absorption and emission spectroscopies as well as single-crystal X-ray diffraction. [Eu2L2(CH3COO)4(CH3OH)2] (1) and [Gd2L2(CH3COO)4(CH3OH)2] (2) are iso-structures, each consisting of two M : L : CH3COO : CH3OH (1 : 1 : 1 : 1) units bridged by two acetate anions with the metal center in a distorted capped square antiprismatic coordination geometry. Their vibration modes, electronic structures, and photoluminescent properties are reported. © 2016 Taylor & Francis Group
Gov't Doc #: 8999
URI: http://dx.doi.org/10.1080/00958972.2016.1194403
http://apo.ansto.gov.au/dspace/handle/10238/9101
ISSN: 0095-8972
Appears in Collections:Journal Articles

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