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Title: | Tuning pore size in a zirconium–tricarboxylate metal–organic framework |
Authors: | Liang, WB Chevreau, H Ragon, F Southon, PD Peterson, VK D'Alessandro, DM |
Keywords: | Zirconium Acetates Ligands Metals Carboxylation Porosity |
Issue Date: | 4-Jun-2014 |
Publisher: | Royal Society of Chemistry |
Citation: | Liang, W., Chevreau, H., Ragon, F., Southon, P. D., Peterson, V. K., & D'Alessandro, D. M. (2014). Tuning pore size in a zirconium-tricarboxylate metal-organic framework. [10.1039/C4CE01031K]. CrystEngComm, 16(29), 6530-6533. doi:10.1039/c4ce01031k |
Abstract: | The water-stable zirconium–tricarboxylate series of frameworks, [Zr6O4(OH)4(X)6(btc)2]·nH2O, where X = formate (F), acetate (A), or propionate (P), exhibit tunable porosity by virtue of systematic modulation of the chain length of the monocarboxylate ligand X. This modification not only impacts the pore size of the framework, but provides an important avenue for the construction of mixed-linker MOFs. © 2014, The Royal Society of Chemistry. |
Gov't Doc #: | 7099 |
URI: | http://dx.doi.org/10.1039/c4ce01031k http://apo.ansto.gov.au/dspace/handle/10238/7517 |
ISSN: | 1466-8033 |
Appears in Collections: | Journal Articles |
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