Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/5517
Title: Zinc Hydroxyapatite Catalyst for Decomposition of 2-Propanol
Authors: Low, HR
Avdeev, M
Ramesh, K
White, TJ
Keywords: Calcium phosphates
Carbon dioxide
Oxidation
Alchols
Ions
Crystallography
Issue Date: 8-Aug-2012
Publisher: Wiley-V C H Verlag GMBH
Citation: Low, H. R., Avdeev, M., Ramesh, K., & White, T. J. (2012). Zinc Hydroxyapatite Catalyst for Decomposition of 2-Propanol [Special Issue]. Advanced Materials, 24(30), 4175-4179. doi:10.1002/adma.201104755
Abstract: Hydroxyapatite (HAp) is attracting interest as a heterogeneous catalyst due to its “zeolitic” properties that allow tailoring of chemically active surface sites for specific applications. Here, the crystallographic modification of HAp through incorporation of zinc (Zn2+) was studied using diffraction and spectroscopic techniques. The preferential displacement of tunnel calcium (Ca2+) by covalently bonded Zn2+ inhibits crystal growth and promotes the retention of an amorphous (10-20 wt%) component. In combination, these factors create chemically active surfaces that allow Zn-HAp materials to effectively absorb carbon monoxide (*characteristic vibration at ~1711 cm-1) and catalyze the decomposition of 2-propanol. © 2012, Wiley-VCH Verlag GmbH & Co. KGaA
Gov't Doc #: 4629
URI: http://dx.doi.org/10.1002/adma.201104755
http://apo.ansto.gov.au/dspace/handle/10238/5517
ISSN: 0935-9648
Appears in Collections:Journal Articles

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