Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/4350
Title: In situ neutron diffraction under high pressure-Providing an insight into working catalysts
Authors: Kandemir, T
Wallacher, D
Hansen, TC
Liss, KD
d'Alnoncourt, RN
Schlogl, R
Behrens, M
Keywords: Neutron diffraction
Heterogeneous catalysis
Correlations
Measuring instruments
Diffraction
Equipment
Issue Date: 1-May-2012
Publisher: Elsevier
Citation: Kandemir, T., Wallacher, D., Hansen, T., Liss, K. D., d'Alnoncourt, R. N., Schlogl, R., Behrens, M. (2012). In situ neutron diffraction under high pressure-Providing an insight into working catalysts. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment Volume 673, 1 May 2012, Pages 51-55 Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 673, 51-55. doi:10.1016/j.nima.2012.01.019
Abstract: In the present work the construction and application of a continuous flow cell is presented, from which neutron diffraction data could be obtained during catalytic reactions at high pressure. By coupling an online gas detection system, parallel structure and activity investigations of working catalysts under industrial relevant conditions are possible. The flow cell can be operated with different feed gases in a wide range from room temperature to 603 K. Pressures from ambient up to 6 MPa are applicable. An exchangeable sample positioning system makes the flow cell suitable for several different goniomter types on a variety of instrument beam lines. Complementary operational test measurements were carried out monitoring reduction of and methanol synthesis over a Cu/ZnO/Al2O3 catalyst at the high-flux powder diffraction beamline D1B at ILL and high-resolution diffraction beamline Echidna at ANSTO. (C) 2012 Elsevier B.V.
Gov't Doc #: 4421
URI: http://dx.doi.org/10.1016/j.nima.2012.01.019
http://apo.ansto.gov.au/dspace/handle/10238/4350
ISSN: 0168-9002
Appears in Collections:Journal Articles

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