Please use this identifier to cite or link to this item:
https://apo.ansto.gov.au/dspace/handle/10238/2999
Title: | Neutron diffraction study of phase transitions in perovskite-type strontium molybdate SrMoO3 |
Authors: | Macquart, RB Kennedy, BJ Avdeev, M |
Keywords: | Perovskite Phase transformations Neutron diffraction Electrical properties Strontium Molybdates |
Issue Date: | Jan-2010 |
Publisher: | Elsevier |
Citation: | Macquart, R. B., Kennedy, B. J., & Avdeev, M. (2010). Neutron diffraction study of phase transitions in perovskite-type strontium molybdate SrMoO3. Journal of Solid State Chemistry, 183(1), 250-255. doi:10.1016/j.jssc.2009.11.005 |
Abstract: | The structure of a polycrystalline sample of SrMoO3 has been investigated using powder neutron diffraction from 5 to 300 K, to reveal two structural phase transitions, the first from the cubic structure with a=3.97629(3) Å to a tetragonal structure in I4/mcm near 266 K and the second to an orthorhombic Imma phase below 125 K. The average Mo–O distance is essentially independent of temperature. The temperature dependence of the octahedral tilting appears typical of a tricritical phase transition. © 2009, Elsevier Ltd. |
Gov't Doc #: | 1469 |
URI: | http://dx.doi.org/10.1016/j.jssc.2009.11.005 http://apo.ansto.gov.au/dspace/handle/10238/2999 |
ISSN: | 0022-4596 |
Appears in Collections: | Journal Articles |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.