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https://apo.ansto.gov.au/dspace/handle/10238/2999| Title: | Neutron diffraction study of phase transitions in perovskite-type strontium molybdate SrMoO3. |
| Authors: | Macquart, RB Kennedy, BJ Avdeev, M |
| Keywords: | Perovskite Phase transformations Neutron diffraction Electrical properties Strontium Molybdates |
| Issue Date: | Jan-2010 |
| Publisher: | Elsevier |
| Citation: | Macquart, R. B., Kennedy, B. J., & Avdeev, M. (2010). Neutron diffraction study of phase transitions in perovskite-type strontium molybdate SrMoO3. Journal of Solid State Chemistry, 183(1), 250-255. doi:10.1016/j.jssc.2009.11.005 |
| Abstract: | The structure of a polycrystalline sample of SrMoO3 has been investigated using powder neutron diffraction from 5 to 300 K, to reveal two structural phase transitions, the first from the cubic structure with a=3.97629(3) Å to a tetragonal structure in I4/mcm near 266 K and the second to an orthorhombic Imma phase below 125 K. The average Mo–O distance is essentially independent of temperature. The temperature dependence of the octahedral tilting appears typical of a tricritical phase transition. © 2009, Elsevier Ltd. |
| Gov't Doc #: | 1469 |
| URI: | http://dx.doi.org/10.1016/j.jssc.2009.11.005 http://apo.ansto.gov.au/dspace/handle/10238/2999 |
| ISSN: | 0022-4596 |
| Appears in Collections: | Journal Articles |
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