Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/12525
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dc.contributor.authorRen, QY-
dc.contributor.authorHutchison, WD-
dc.contributor.authorWang, JL-
dc.contributor.authorStuder, AJ-
dc.contributor.authorCadogan, JM-
dc.contributor.authorCampbell, SJ-
dc.date.accessioned2021-12-17T00:28:00Z-
dc.date.available2021-12-17T00:28:00Z-
dc.date.issued2017-02-01-
dc.identifier.citationRen, Q. Y., Hutchison, W. D., Wang, J. L., Studer, A. J., Cadogan, J. M., & Campbell, S. J. (2017). Magnetic and structural transitions in magnetocaloric Mn(Co1-xNix)Ge alloys. Paper presented to the 41st Annual Condensed Matter and Materials Meeting, Charles Sturt University, Wagga Wagga, NSW, Australia,31st January - 3rd February 2017. (pp.36). Retrieved from: https://physics.org.au/wp-content/uploads/cmm/2017/Wagga_2017_Conference_Handbook.pdfen_US
dc.identifier.otherWA1-
dc.identifier.urihttps://physics.org.au/wp-content/uploads/cmm/2017/Wagga_2017_Conference_Handbook.pdfen_US
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/12525-
dc.description.abstractThe magnetocaloric effect (MCE) - a significant temperature change due to the entropy change around magnetic transitions in materials driven by magnetisation or demagnetisation - has emerged as an increasingly important topic in condensed matter physics in the past two decades. A direct (positive) MCE occurs around a magnetic transition from ferromagnetism (FM) to paramagnetism (PM), while an inverse (negative) MCE is obtained around a magnetic transition from antiferromagnetism (AFM) to FM. If such magnetic transitions couple with a structural transition, a first-order magneto-structural transition can form and hence strengthen the MCE. In this work, the magnetic and structural transitions have been tuned by substitution of Ni for Co in MnCoGe. The Mn(Co1-xNix)Ge samples (x = 0.14 - 1.00) were studied by magnetisation, x-ray and neutron powder diffraction measurements over the temperature range 5 - 450 K. Mn(Co1-xNix)Ge alloys have an orthorhombic (Orth) TiNiSi-type structure (Pnma) at low temperature with transformation to a hexagonal (Hex) Ni2In-type structure (P63/mmc) at the martensitic transformation temperature TM. The increase of the Ni content changes the orthorhombic phase from FM (x < 0.55) to spiral-AFM (x ≥ 0.55). In addition, the transformation temperature TM for the reverse martensitic transformation - from orthorhombic to hexagonal - decreases with Ni content x when x < 0.55 and then increases when x ≥ 0.55. The adjustment of TM leads to the occurrences of first-order FM-Orth/PM-Hex magneto-structural transitions and large values of the direct MCE in the samples with ~0.20 < x < ~0.60. Moreover, the spiral-AFM/FM magnetic transitions in the orthorhombic phase for samples with ~0.55 < x < ~0.75 result in an inverse MCE.en_US
dc.language.isoenen_US
dc.publisherAustralian Institute of Physicsen_US
dc.subjectCoherent scatteringen_US
dc.subjectDiffractionen_US
dc.subjectElementsen_US
dc.subjectMetalsen_US
dc.subjectPhysical propertiesen_US
dc.subjectScatteringen_US
dc.subjectThermodynamic propertiesen_US
dc.subjectTransition elementsen_US
dc.subjectMagneto-thermal effectsen_US
dc.titleMagnetic and structural transitions in magnetocaloric Mn(Co1-xNix)Ge alloysen_US
dc.typeConference Presentationen_US
dc.date.statistics2021-09-24-
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