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- Item2D cobalt based coordination polymer constructed from benzimidazole and acetate ion exhibiting spin-canted antiferromagnetism(Royal Society of Chemistry, 2010-05-07) Arai, L; Nadeem, MA; Bhadbhade, MM; Stride, JAA coordination polymer, [CoII(bIM)(acetate)] (bIM = benzimidazole) was synthesized using a solvothermal method; the complex has a two dimensional non-interpenetrated network structure and exhibits a spin-canted antiferromagnetic behaviour at low temperature and a high coercive field. © 2010, Royal Society of Chemistry
- ItemTuning pore size in a zirconium–tricarboxylate metal–organic framework(Royal Society of Chemistry, 2014-06-04) Liang, WB; Chevreau, H; Ragon, F; Southon, PD; Peterson, VK; D'Alessandro, DMThe water-stable zirconium–tricarboxylate series of frameworks, [Zr6O4(OH)4(X)6(btc)2]·nH2O, where X = formate (F), acetate (A), or propionate (P), exhibit tunable porosity by virtue of systematic modulation of the chain length of the monocarboxylate ligand X. This modification not only impacts the pore size of the framework, but provides an important avenue for the construction of mixed-linker MOFs. © 2014, The Royal Society of Chemistry.