Browsing by Author "Forcén-Vázquez, E"

Now showing 1 - 1 of 1
  • No Thumbnail Available
    Item
    Proton cascade in a molecular solid: H/D exchange on mobile and immobile water
    (Wiley, 2013-12-09) Capelli, SC; Falvello, LR; Forcén-Vázquez, E; McIntyre, GJ; Palacio, F; Sanz, S; Tomás, M
    Working without pores: In non-porous, channel-free crystals of a manganese citrate coordination polymer, neutron diffraction reveals that the water molecules, both metal-bound and co-crystallized, undergo full hydrogen/deuterium exchange. Neutron diffraction analyses show a pattern of hydrogen disorder that can be interpreted in terms of the Grotthuss proton-cascade mechanism. © 1999-2020 John Wiley & Sons, Inc.