ANSTO :: Browsing by Author "Rau, GC"

Browsing by Author "Rau, GC"

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Cave monitoring to constrain the paleoclimate interpretation of δ18O proxy in speleothems from semi-arid areas
(University of New South Wales and Australian Nuclear Science and Technology Organisation, 2015-07-09) Markowska, M; Baker, AA; Andersen, MS; Jex, CN; Cuthbert, MO; Rau, GC; Graham, PW; Rutlidge, H; Mariethoz, G; Marjo, CE; Treble, PC; Edwards, N
Not supplied to the ANSTO Library.
Cave stalagmites as records of past recharge frequency in semi-arid Australia
(National Centre for Groundwater Research And Training, 2015-11-03) Markowska, M; Baker, AA; Andersen, MS; Rutlidge, H; Jex, CN; Cuthbert, MO; Rau, GC; Adler, L; Graham, PW; Mariethoz, G; Marjo, CE; Treble, PC
Understanding past variability in groundwater recharge over recent time scales (0 – 10 ka) in Australia is essential for future sustainable groundwater management in a changing climate. Currently, there are limited data about past infiltration rates and their relationship to environmental controls that dominate recharge variability. Speleothem (cave precipitates) records may provide a new approach to understanding past infiltration (i.e. recharge rates), in addition to traditional interpretations of connectivity between climate and the hydrological cycle, in drier parts of Australia. In this study we used Cathedral Cave, (SE Australia) located in a temperate semi-arid climate, as a natural laboratory to investigate cave infiltration rates and the climate-karst-cave interactions driving the isotopic (δ18O) and chemical variability in modern drip water. These findings were then used to interpret the δ18O stalagmite record from two modern speleothems growing during the last ~50 years. Modern drip water results showed that the δ18O composition was enriched by up to 2.77 ‰ relative to annually weighted mean rainfall. Isotopically lighter δ18O occurred during infiltration events, followed by subsequent isotopic enrichment as evaporation in the unsaturated zone fractionated δ18O of stored water. Drip rate monitoring revealed that larger events leading to infiltration were infrequent (0 – 3 a-1) and the ‘effectiveness’ of these infiltration events was controlled by antecedent moisture conditions in the soil zone. In drier climatic zones, evaporation drives the enrichment of δ18O in the unsaturated zone, allowing periods of infiltration to be identified from the stable isotopic composition of drip waters. Our findings are important for interpreting speleothem records from regions with infrequent recharge and high evaporation rates. Such records are likely to contain evidence of past infiltration events moderated by an evaporation signal, allowing records of paleo-recharge to be reconstructed for drier climate regions of Australia.
Climate and groundwater recharge: the story from Australian caves
(National Centre for Groundwater Research And Training, 2017-07-11) Baker, AA; Treble, PC; Markowska, M; Andersen, MS; Wang, Z; Mahmud, K; Cuthbert, MO; Coleborn, K; Rau, GC
Quantifying the timing and extent of diffuse groundwater recharge is crucial for our understanding of groundwater recharge processes. However, diffuse recharge is notably difficult to measure directly. Caves can be used as natural observatories of ongoing diffuse recharge processes, and speleothems (cave carbonate deposits such as stalagmites) as archives of past recharge. Cave records can improve our understanding of diffuse recharge in the context of climate change and past climate variability. A long-term, national monitoring program of infiltration into caves has been undertaken since 2010 using a network of over 200 automated loggers. This has been supplemented by artificial irrigation experiments at one semi-arid site. The timing of past recharge can be determined from the periods of past stalagmite growth. Recharge characteristics can be elucidated from oxygen isotope composition, with increased 18O likely caused by evaporative fractionation and increased 16O from high intensity/magnitude rainfall events. Automated logger data identify the diffuse recharge thresholds that vary with climate and geology. Both the logged data of natural events and the artificial irrigation experiments identify significant spatial heterogeneity in recharge in these karstified systems. Water infiltrating into the karst is often depleted in the lighter oxygen isotope due to soil and shallow subsurface evaporative fractionation. Speleothem deposition is more frequent during glacial periods, presumably because recharge thresholds are lower, and their isotopic composition provides evidence of the characteristics of the recharge process. Caves provide direct access into the unsaturated zone. Direct observation of groundwater recharge can be used to complement data from the saturated zone (boreholes) and models. The heterogeneity of recharge in karst aquifers can be directly observed and quantified. Speleothems preserve a record of groundwater recharge that can extend back for hundreds of thousands of years, providing a long-term view on the timing and variability of groundwater recharge in Australia.
Constraining water fluxes through the streambed of a semi-arid losing stream using natural tracers: heat and radioisotopes
(American Geophysical Union, 2011-12-05) Andersen, MS; Rau, GC; McCallum, AM; Meredith, KT; Acworth, RI
Natural physical and chemical tracers of flow have different advantages and shortfalls based on their properties and the uncertainty related to variability in their source concentration. Each tracer integrates over a characteristic spatial-temporal scale depending on its decay or production rate and the flow velocity of the system. For instance heat tracing using diurnal temperature fluctuations will, at best, provide information about flow in the upper 1-2 m of the streambed before the signal is dampened below measurement resolution (Constantz et al. 2003). Conversely, radioisotopes used as tracers will integrate over increasing spatio-temporal scales for decreasing decay constants. Radioisotopes with comparatively slow decay rates will be less sensitive for resolving flow conditions on short spatio-temporal scales. Therefore, it is difficult to use these tracers in the streambed of losing systems because the radioactive decay is not discernible against the variability. Consequently, employing a combination of different tracers provides information on different parts of a given flow system. Comparing flow velocities derived from tracers integrating over different scales allows for separating the local hyporheic exchange from the regional groundwater recharge. A field experiment was carried out in a perennial section of the mostly ephemeral Maules Creek in NSW, Australia. Streambed temperature profiles were monitored at three sites along a 400 m stretch of the perennial reach. Streambed temperatures were recorded at 4 depths within one meter below the streambed. Water samples were collected from surface water, streambed and groundwater and analysed for stable water isotopes (18O and 2H) and radioisotopes (222Rn and 3H). The streambed heat profiles provided time series of surface water/groundwater exchange. Using this method it was found that the conditions were losing at all three sites with recharge rates varying between 0 and 0.4 m/d. 222Rn measurements in the surface water along the perennial reach qualitatively identified losing and gaining sections of the stream with low and high 222Rn activities, respectively. One of the losing sections of the stream was instrumented with a transect of groundwater piezometers. In this transect, 3H levels of 1.3-1.5 TU were measured, comparable to surface waters, indicating recent groundwater recharge. However, the variations in 3H combined with the analysis uncertainty did not allow for a recharge estimate. 222Rn with its half-life of only 3.8 d proved more useful. A zone of low 222Rn activity was found as deep as 6-7 m below the stream, corroborating the 3H and temperature data. Regional groundwater 222Rn activities were used to estimate the secular equilibrium activity of Rn. Residence times of 1 to 7 days were calculated based on these estimates. Converted to Darcy velocities of 0.2-1.7 m/d these values generally agree with the velocities derived from the temperature data indicating that the measured fluxes from the temperature data represent recharge rates and not simply hyporheic exchange. © American Geophysical Union.
Dripwater organic matter and trace element geochemistry in a semi-arid karst environment: Implications for speleothem paleoclimatology
(Elsevier, 2014-06-15) Rutlidge, H; Baker, AA; Marjo, CE; Andersen, MS; Graham, PW; Cuthbert, MO; Jex, CN; Rau, GC; Roshan, H; Markowska, M; Mariethoz, G
A series of four short-term infiltration experiments which revealed hydrochemical responses relevant to semi-arid karst environments were carried out above Cathedral Cave, Wellington, New South Wales (NSW), Australia. Dripwater samples were collected at two sites for trace element and organic matter analysis. Organic matter was characterised using fluorescence and interpreted using a PARAFAC model. Three components were isolated that represented unprocessed, soil-derived humic-like and fulvic-like material, processed humic/fulvic-like material and tryptophan-like fluorescence. Principal Component Analysis (PCA) performed on the entire dataset comprising trace element concentrations and PARAFAC scores revealed two dominant components that were identified as soil and limestone bedrock. The soil component was assigned based on significant contributions from the PARAFAC scores and additionally included Ba, Cu, Ni and Mg. The bedrock component included the expected elements of Ca, Mg and Sr as well as Si. The same elemental behaviour was observed in recent stalagmite growth collected from the site. Our experiments demonstrate that existing paleoclimate interpretations of speleothem Mg and Sr, developed in regions of positive water balance, are not readily applicable to water limited environments. We provide a new interpretation of trace element signatures unique to speleothems from water limited karst environments. © 2014, Elsevier Ltd.
Evaporative cooling of speleothem drip water
(Nature Publishing Group, 2014-06-04) Cuthbert, MO; Rau, GC; Andersen, MS; Roshan, H; Rutlidge, H; Marjo, CE; Markowska, M; Jex, CN; Graham, PW; Mariethoz, G; Acworth, RI; Baker, AA
This study describes the first use of concurrent high-precision temperature and drip rate monitoring to explore what controls the temperature of speleothem forming drip water. Two contrasting sites, one with fast transient and one with slow constant dripping, in a temperate semi-arid location (Wellington, NSW, Australia), exhibit drip water temperatures which deviate significantly from the cave air temperature. We confirm the hypothesis that evaporative cooling is the dominant, but so far unattributed, control causing significant disequilibrium between drip water and host rock/air temperatures. The amount of cooling is dependent on the drip rate, relative humidity and ventilation. Our results have implications for the interpretation of temperature-sensitive, speleothem climate proxies such as delta O-18, cave microecology and the use of heat as a tracer in karst. Understanding the processes controlling the temperature of speleothem-forming cave drip waters is vital for assessing the reliability of such deposits as archives of climate change. © 2014, Nature Publishing Group.
A groundwater recharge experiment in krast - Wellington Caves, NSW
(International Association of Hydrogeologists, 2013-09-16) Andersen, MS; Baker, AA; Graham, PW; Rutlidge, H; Mariethoz, G; Roshan, H; Rau, GC; Markowska, M; Cuthbert, MO
Groundwater recharge is a process which is inherently difficult to measure directly due to soil and sediment heterogeneity and the tendency for this to cause preferential flow. This often leads to groundwater recharge being estimated by indirect methods, such as remotely or by differences in the water balance, which frequently causes huge uncertainties in the estimates. Karst terrains with cave features, although notoriously heterogeneous, offer a rare opportunity to physically enter the subsurface and make direct observations. Cathedral Cave at Wellington Caves in NSW, Australia was used for a multiple tracer experiment to look a recharge processes as well as physical and chemical processes affecting speleothems formation. On four consecutive days, four water releases were applied to a 3 x 7 m soil patch 2-3 m above the cave ceiling. The applications varying from 800 to 1500 L corresponds to natural precipitation events of 40 to 70 mm, events which have been known to cause recharge into the caves in the past. The four different events were variably modified by adding deuterium (2H), a fluorescing tracer and ice to reduce the temperature. Inside the caves onset of recharge was measured by automatic drip rate monitoring and temperature loggers. In addition, discrete water samples were collected and analysed for stable water isotope composition, fluorescence and dissolved trace elements. A preliminary assessment of the cave observations suggest that. although ow was preferentially along fractures, considerable interaction with pore water in the rock matrix must have taken place to significantly dilute the tracer content of water sampled in the cave. To our knowledge this is the first time that is has been directly shown that water sampled during a recharge event is only fractionally water from that particular event. For the location of this study the result is surprising considering the short distance of 2-3 m between the soil surface and the cave ceiling. The results have significant implications for our understanding of karst hydrology as well as reconstruction of past recharge and climate conditions from cave speleothems.
Semi-arid zone caves: evaporation and hydrological controls on δ18O drip water composition and implications for speleothem paleoclimate reconstructions
(Elsevier B.V., 2016-01-01) Markowska, M; Baker, AA; Andersen, MS; Jex, CN; Cuthbert, MO; Rau, GC; Graham, PW; Rutlidge, H; Mariethoz, G; Marjo, CE; Treble, PC; Edwards, N
Oxygen isotope ratios in speleothems may be affected by external processes that are independent of climate, such as karst hydrology and kinetic fractionation. Consequently, there has been a shift towards characterising and understanding these processes through cave monitoring studies, particularly focussing on temperate zones where precipitation exceeds evapotranspiration. Here, we investigate oxygen isotope systematics at Wellington Caves in semi-arid, SE Australia, where evapotranspiration exceeds precipitation. We use a novel D2O isotopic tracer in a series of artificial irrigations, supplemented by pre-irrigation data comprised four years of drip monitoring and three years of stable isotope analysis of both drip waters and rainfall. This study reveals that: (1) evaporative processes in the unsaturated zone dominate the isotopic composition of drip waters; (2) significant soil zone ‘wetting up’ is required to overcome soil moisture deficits in order to achieve infiltration, which is highly dependent on antecedent hydro-climatic conditions; (3) lateral flow, preferential flow and sorption in the soil zone are important in redistributing subsurface zone water; (4) isotopic breakthrough curves suggest clear evidence of piston-flow at some drip sites where an older front of water discharged prior to artificial irrigation water; and (5) water residence times in a shallow vadose zone (<2 m) are highly variable and can exceed six months. Oxygen isotope speleothem records from semi-arid regions are therefore more likely to contain archives of alternating paleo-aridity and paleo-recharge, rather than paleo-rainfall e.g. the amount effect or mean annual. Speleothem-forming drip waters will be dominated by evaporative enrichment, up to ∼3‰ in the context of this study, relative to precipitation-weighted mean annual rainfall. The oxygen isotope variability of such coeval records may further be influenced by flow path and storage in the unsaturated zone that is not only drip specific but also influenced by internal cave climatic conditions, which may vary spatially in the cave.© 2015, Elsevier Ltd.
Use of stable and radioactive isotopes to unravel surface water groundwater interactions in developed catchment
(International Atomic Energy Agency, 2015-01-01) Andersen, MS; Rau, GC; Meredith, KT; McCallum, AM; Acworth, RI
Abstract: Traditionally surface water groundwater interactions are estimated using hydrometric and water balance methods. However, the hydrometric methods, based on hydraulic gradients, have huge uncertainties related to the mostly unknown and often highly heterogeneous permeability distribution. Similarly, the surface water groundwater exchange can be relatively small compared to other components of the water balance (e.g. differential steam flow gauging) and consequently its estimation is associated with large uncertainties when using a water balance method. Environmental tracers such as isotopes on the other hand integrate what has actually taken place. However, each individual isotopic tracer has particular advantages and disadvantages and therefore limited use. For instance each radioactive isotope is limited to provide residence time estimations within a certain age range whereas stable isotopes only work when different water sources have distinctly different isotopic compositions. In this study, of a highly developed catchment subject to groundwater depletion it is demonstrated that by combining different tracers (14C, 3H, 2H and 18O) a more complete picture of the surface water groundwater interactions can be obtained.
What controls the cave drip water temperature? Analysis and implications for paleoclimate reconstruction from speleothems
(National Centre for Groundwater Research And Training, 2015-11-03) Rau, GC; Cuthbert, MO; Andersen, MS; Baker, AA; Rutlidge, H; Markowska, M; Roshan, H; Marjo, CE; Graham, PW; Ackworth, RI
Cave drip water temperature influences cave hydrobiochemical processes and also speleothem based paleoclimate signals (e.g. biomarkers, isotopes, etc). Yet very little is known about what controls cave drip water temperature. This experimental investigation reveals the dominant heat transfer mechanisms. Design and Methodology: A shallow cave drip water flow path along a flowstone was instrumented with a number of high resolution temperature sensors and drip loggers. Cave and surface climate parameters: Pressure, Relative Humidity (RH) and Temperature were monitored with high frequency. Three separate land surface irrigation experiments were conducted comprising of multiple applications of water at the surface above the cave. One of the irrigation batched was enriched with deuterium (610% VSMOW) as a conservative tracer. The cave drip water temperature measurements clearly reveal the presence of all common heat transport mechanisms (e.g. conduction, convection, latent heat exchange). In general, the cave drip water has the same temperature as the subsurface conduction profile of the rock at that depth. However, at fast flow rates the warmer/colder signal during summer/winter is being washed down convectively leading to temperature anomalies of up 1.5 °C. Importantly, daily cave venting reduces the cave RH thus leading to evaporative cooling of drip water of up -2.5 °C. Cave drip water temperature is mainly controlled by the subsurface heat conduction profile as well as the cave climate. This, however, depends on the drip rate and length of flow path exposed to the cave air. Paleoclimate reconstruction requires depth-dependent deconvolution of the subsurface conduction signal as well as consideration of past or present cave venting and evaporative cooling.
Where is the water going: an irrigation experiment using a natural isotopic tracer in karst SE, Australia
(European Geosciences Union, 2014-05) Markowska, M; Baker, AA; Andersen, MS; Cuthbert, MO; Rau, GC; Jex, CN; Rutlidge, H; Marjo, CE; Roshan, H; Treble, PC
The karst unsaturated zone is a fractured rock environment associated with very heterogeneous water movement; spatial variability in the subsurface water storage; and fast preferential flow through fractures and fissures. These factors dominate the way in which water moves within the unsaturated zone in these environments, giving rise to flow path complexities less common in homogenous media. Currently there is limited research regarding karst infiltration/storage processes and potential evaporation in the unsaturated zone. Such processes may have the potential to alter the stable isotopic composition of groundwater. Caves provide a unique environment within which to examine exfiltration variability and flow dynamics in situ. In semi-arid environments evaporative processes in the unsaturated zone have been shown to directly alter the isotopic δ18O composition of cave drip waters, fractionating them towards heavier ratios, by a magnitude of 1-3 per mil relative to mean annual rainfall (Bar Matthews et al., 1996; Cuthbert et al., 2014). Here we present a novel isotopic drip water study from an artificial infiltration experiment at Wellington Caves, SE Australia. A series of four artificial infiltration events were initiated directly over Cathedral Cave, Wellington over as many days. The first event was spiked with a deuterium tracer and the subsurface response was monitored during several sampling campaigns over the following year. The infiltration study revealed: (1) isotopic break-through curves suggest a front of older water from the unsaturated zone storage arrived ahead of the infiltration water, (2) water residence times in the unsaturated zone were found to be longer than 6 months and, (3) large spatial heterogeneities existed in the proportion of exfiltrated deuterium tracer at different drip sites in the cave suggesting unique pathways and sources of water in the unsaturated zone. Implications from this study include the interpretation of paleo-climate speleothem records from semi-arid to arid environments. © Author(s) 2014.

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