Browsing by Author "Mulvaney, R"

Now showing 1 - 5 of 5
  • Thumbnail Image
    Item
    Atmospheric CO2 and d13C-CO2 reconstruction of the little ice age from antarctic ice cores
    (Copernicus Publications, 2015-04-12) Rubino, M; Etheridge, DM; Trudinger, CM; Allison, CE; Rayner, PJ; Mulvaney, R; Steele, LP; Langenfelds, RL; Sturges, WT; Curran, MAJ; Smith, AM
    The decrease of atmospheric CO2 concentration recorded in Antarctic ice around 1600 AD is one of the most significant atmospheric changes to have occurred during the last millennia, before the onset of the industrial period.Together with the temperature decrease, the CO2 drop has been used to derive the sensitivity of carbon stores to climate. However, the cause of it is still under debate because models are not yet able to reproduce either its magnitude, or its timing. Here we present new measurements of the CO2 concentration decrease recorded in an ice core from a medium accumulation rate site in Antarctica (DML). We show that the new record is compatible(differences <2 ppm) with the CO2 record from the high accumulation rate DSS site on Law Dome (East Antarctica), when the different age distributions are taken into account. We have also measured the d13C-CO2 change in DML ice, filling a gap around 1600 AD in the DSS d13C record. We use a double deconvolution of the CO2 and d13C records together to provide quantitative evidence that the CO2 decrease was caused by a change in the net flux to the terrestrial biosphere. Finally, we provide a new interpretation of a published record showing increasing atmospheric carbonyl sulphide during the CO2 decrease, suggesting that cooler LIA climate affected terrestrial biospheric fluxes. Altogether our findings support the hypothesis that reduced soil heterotrophic respiration is likely to have given the most significant contribution to the LIA CO2 decrease implying a positive CO2-climate feedback. © 2015, Authors.
  • Thumbnail Image
    Item
    A community-based geological reconstruction of Antarctic ice sheet deglaciation since the last glacial maximum
    (Elsevier, 2014-09-15) Bentley, MJ; O'Cofaigh, C; Anderson, JB; Conway, H; Davies, B; Graham, AGC; Hillenbrand, CD; Hodgson, DA; Jamieson, SSR; Larter, RD; Mackintosh, AN; Smith, JA; Verleyen, E; Ackert, RP; Bart, PJ; Berg, S; Brunstein, D; Canals, M; Colhoun, EA; Crosta, X; Dickens, WA; Domack, E; Dowdeswell, JA; Dunbar, R; Ehrmann, W; Evans, J; Favier, V; Fink, D; Fogwill, CJ; Glasser, NF; Gohl, K; Golledge, NR; Goodwin, I; Gore, DB; Greenwood, SL; Hall, BL; Hall, K; Hedding, DW; Hein, AS; Hocking, EP; Jakobsson, M; Johnson, JS; Jomelli, V; Jones, RS; Klages, JP; Kristoffersen, Y; Kuhn, G; Leventer, A; Licht, K; Lilly, K; Lindow, J; Livingstone, SJ; Massé, G; McGlone, MS; McKay, RM; Melles, M; Miura, H; Mulvaney, R; Nel, W; Nitsche, FO; O'Brien, PE; Post, AL; Roberts, SJ; Saunders, KM; Selkirk, PM; Simms, AR; Spiegel, C; Stolldorf, TD; Sugden, DE; van der Putten, N; van Ommen, TD; Verfaillie, D; Vyverman, W; Wagner, B; White, DA; Witus, AE; Zwartz, D
    A robust understanding of Antarctic Ice Sheet deglacial history since the Last Glacial Maximum is important in order to constrain ice sheet and glacial-isostatic adjustment models, and to explore the forcing mechanisms responsible for ice sheet retreat. Such understanding can be derived from a broad range of geological and glaciological datasets and recent decades have seen an upsurge in such data gathering around the continent and Sub-Antarctic islands. Here, we report a new synthesis of those datasets, based on an accompanying series of reviews of the geological data, organised by sector. We present a series of timeslice maps for 20 ka, 15 ka, 10 ka and 5 ka, including grounding line position and ice sheet thickness changes, along with a clear assessment of levels of confidence. The reconstruction shows that the Antarctic Ice sheet did not everywhere reach the continental shelf edge at its maximum, that initial retreat was asynchronous, and that the spatial pattern of deglaciation was highly variable, particularly on the inner shelf. The deglacial reconstruction is consistent with a moderate overall excess ice volume and with a relatively small Antarctic contribution to meltwater pulse 1a. We discuss key areas of uncertainty both around the continent and by time interval, and we highlight potential priorities for future work. The synthesis is intended to be a resource for the modelling and glacial geological community. © 2014 The Authors. CC BY license
  • No Thumbnail Available
    Item
    Low atmospheric CO2 levels during the Little Ice Age due to cooling-induced terrestrial uptake
    (Springer Nature, 2016-07-25) Rubino, M; Etheridge, DM; Trudinger, CM; Allison, CE; Rayner, PJ; Enting, I; Mulvaney, R; Steele, LP; Langenfelds, RL; Sturges, WT; Curran, MAJ; Smith, AM
    Low atmospheric carbon dioxide (CO2) concentration1 during the Little Ice Age has been used to derive the global carbon cycle sensitivity to temperature2. Recent evidence3 confirms earlier indications4 that the low CO2 was caused by increased terrestrial carbon storage. It remains unknown whether the terrestrial biosphere responded to temperature variations, or there was vegetation re-growth on abandoned farmland5. Here we present a global numerical simulation of atmospheric carbonyl sulfide concentrations in the pre-industrial period. Carbonyl sulfide concentration is linked to changes in gross primary production6 and shows a positive anomaly7 during the Little Ice Age. We show that a decrease in gross primary production and a larger decrease in ecosystem respiration is the most likely explanation for the decrease in atmospheric CO2 and increase in atmospheric carbonyl sulfide concentrations. Therefore, temperature change, not vegetation re-growth, was the main cause of the increased terrestrial carbon storage. We address the inconsistency between ice-core CO2 records from different sites8 measuring CO2 and δ13CO2 in ice from Dronning Maud Land (Antarctica). Our interpretation allows us to derive the temperature sensitivity of pre-industrial CO2 fluxes for the terrestrial biosphere (γL = −10 to −90 Pg C K−1), implying a positive climate feedback and providing a benchmark to reduce model uncertainties. © 2016, Nature Publishing Group.
  • Thumbnail Image
    Item
    A record of carbonyl sulfide from Antarctic ice over the last 1000 years
    (Geochemical Society, 2013-01-01) Allin, SJ; Sturges, WT; Laube, JC; Etheridge, DM; Rubino, M; Trudinger, CM; Curran, MAJ; Smith, AM; Mulvaney, R
    Carbonyl sulfide (COS) is a trace gas, present in the troposphere, and also in the stratosphere, where it contributes to the stratospheric sulfate aerosol layer. It has both natural and anthropogenic sources. Natural processes include uptake by plants, while oceans, wetlands, volcanism and biomass burning all contribute to natural COS emissions. We have measured COS in Antarctic ice cores from Dronning Maud Land, drilled in 1998, the DE08 core drilled at Law Dome in 1987, and the DSS0506 core drilled in 2006. Ice samples with COS gas ages between about 1050 AD and the early 20th centrury have been examined. A large volume ice crusher at the CSIRO Marine and Atmospheric Research laboratory was used to extract air from bubbles occluded in the ice cores. These air samples were analysed for CO2, CH4, CO and 13CO2 at CSIRO, and then for COS and several halocarbons at the University of East Anglia on a high sensitivity gas chromatograph/tri-sector mass spectrometer system. Initial results indicate that good sample integrity can be achieved. Measurements from the DML samples indicate low and uniform abundances across the last few hundred years, and at concentrations significantly below those in the modernday atmosphere. Measurements in more recent ice from DE08 show the start of increasing concentrations in the early 1900s, confirming earlier evidence that the global atmospheric abundance of COS has increased as a result of industrial activity during the 20th century.
  • Thumbnail Image
    Item
    Terrestrial uptake due to cooling responsible for low atmospheric CO2 during the Little Ice Age
    (Antarctic Climate and Ecosystems Cooperative Research Centre, 2016-03-07) Rubino, M; Etheridge, DM; Trudinger, CM; Allison, CE; Rayner, PJ; Enting, I; Mulvaney, R; Steele, LP; Langenfelds, RL; Sturges, WT; Curran, MAJ; Smith, AM
    Models of future carbon cycle-climate changes predict a large range in atmospheric CO2, mainly because of uncertainties in the response of the land carbon cycle to the future temperature increase. The Little Ice Age (LIA, 1500-1750 AD) CO2 decrease is the most significant pre-industrial atmospheric change over the last millennia and has been used to derive the climate sensitivity of the global carbon cycle (δ). While a recent study confirms that pre-industrial CO2 variations were caused by changes in land carbon stores, there are open questions about the size of the atmospheric LIA CO2 decrease reconstructed from ice cores, and about what caused the land to sequester CO2. To quantify the size of the LIA CO2 decrease, we have produced new CO2 measurements from DML ice, that support the DSS LIA CO2 decrease as a real atmospheric feature. To partition the contribution of ocean and land, we have measured the δ 13C-CO2, showing that the cause of the CO2 drop was uptake by the terrestrial biosphere. To identify whether the land uptake was caused by temperature, or by a decline in farming due to pandemics, we have simulated the effect of a temperature perturbation on atmospheric Carbonyl Sulfide (COS). In agreement with the previously published positive COS anomaly, our results indicate that Global Primary Productivity (GPP) decreased during the LIA, ruling out the early anthropogenic land use change hypothesis as the dominant cause of increased terrestrial carbon storage. This allows us to obtain a new, more coherent estimation of δ in the range -10/-60 Pg of C K-1.