Browsing by Author "Isola, I"
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- ItemMagnesium in subaqueous speleothems as a potential palaeotemperature proxy(Springer Nature, 2020-10-06) Drysdale, RN; Couchoud, I; Zanchetta, G; Isola, I; Regattieri, E; Hellstrom, JC; Govin, A; Tzedakis, PC; Ireland, T; Corrick, E; Grieg, A; Wong, HKY; Piccini, L; Holden, PJ; Woodhead, JDFew palaeoclimate archives beyond the polar regions preserve continuous and datable palaeotemperature proxy time series over multiple glacial-interglacial cycles. This hampers efforts to develop a more coherent picture of global patterns of past temperatures. Here we show that Mg concentrations in a subaqueous speleothem from an Italian cave track regional sea-surface temperatures over the last 350,000 years. The Mg shows higher values during warm climate intervals and converse patterns during cold climate stages. In contrast to previous studies, this implicates temperature, not rainfall, as the principal driver of Mg variability. The depositional setting of the speleothem gives rise to Mg partition coefficients that are more temperature dependent than other calcites, enabling the effect of temperature change on Mg partitioning to greatly exceed the effects of changes in source-water Mg/Ca. Subaqueous speleothems from similar deep-cave environments should be capable of providing palaeotemperature information over multiple glacial-interglacial cycles. © 2020 The Author(s)
- ItemPartitioning of Mg, Sr, Ba and U into a subaqueous calcite speleothem(Elsevier, 2019-11-01) Drysdale, RN; Zanchetta, G; Baneschi, I; Guidi, M; Isola, I; Couchoud, I; Piccini, L; Greig, A; Wong, HKY; Woodhead, JD; Regattieri, E; Corrick, E; Paul, B; Spötl, C; Denson, E; Gordon, J; Jaillet, S; Dux, F; Hellstrom, JCThe trace-element geochemistry of speleothems is becoming increasingly used for reconstructing palaeoclimate, with a particular emphasis on elements whose concentrations vary according to hydrological conditions at the cave site (e.g. Mg, Sr, Ba and U). An important step in interpreting trace-element abundances is understanding the underlying processes of their incorporation. This includes quantifying the fractionation between the solution and speleothem carbonate via partition coefficients (where the partitioning (D) of element X (DX) is the molar ratio [X/Ca] in the calcite divided by the molar ratio [X/Ca] in the parent water) and evaluating the degree of spatial variability across time-constant speleothem layers. Previous studies of how these elements are incorporated into speleothems have focused primarily on stalagmites and their source waters in natural cave settings, or have used synthetic solutions under cave-analogue laboratory conditions to produce similar dripstones. However, dripstones are not the only speleothem types capable of yielding useful palaeoclimate information. In this study, we investigate the incorporation of Mg, Sr, Ba and U into a subaqueous calcite speleothem (CD3) growing in a natural cave pool in Italy. Pool-water measurements extending back 15 years reveal a remarkably stable geochemical environment owing to the deep cave setting, enabling the calculation of precise solution [X/Ca]. We determine the trace element variability of ‘modern’ subaqueous calcite from a drill core taken through CD3 to derive DMg, DSr, DBa and DU then compare these with published cave, cave-analogue and seawater-analogue studies. The DMg for CD3 is anomalously high (0.042 ± 0.002) compared to previous estimates at similar temperatures (∼8 °C). The DSr (0.100 ± 0.007) is similar to previously reported values, but data from this study as well as those from Tremaine and Froelich (2013) and Day and Henderson (2013) suggest that [Na/Sr] might play an important role in Sr incorporation through the potential for Na to outcompete Sr for calcite non-lattice sites. DBa in CD3 (0.086 ± 0.008) is similar to values derived by Day and Henderson (2013) under cave-analogue conditions, whilst DU (0.013 ± 0.002) is almost an order of magnitude lower, possibly due to the unusually slow speleothem growth rates (<1 μm a−1), which could expose the crystal surfaces to leaching of uranyl carbonate. Finally, laser-ablation ICP-MS analysis of the upper 7 μm of CD3, regarded as ‘modern’ for the purposes of this study, reveals considerable heterogeneity, particularly for Sr, Ba and U, which is potentially indicative of compositional zoning. This reinforces the need to conduct 2D mapping and/or multiple laser passes to capture the range of time-equivalent elemental variations prior to palaeoclimate interpretation. © 2019 Elsevier Ltd
- ItemRadiometrically dated speleothem records of Terminations IV and V and linkages to the North Atlantic(International Union for Quaternary Research (INQUA), 2019-07-28) Pollard, T; Drysdale, RN; Woodhead, JD; Edwards, RL; Hellstrom, JC; Cheng, H; Dux, F; Daëron, M; Li, XL; Wong, HKY; Couchoud, I; Regattieri, E; Zanchetta, G; Isola, IPaleoclimate archives tied to accurate and precise chronologies are crucial for developing a dynamical understanding of the causes and nature of Quaternary glacial terminations [1]. While numerous well-dated archives provide good chronological control through Terminations I and II, there is presently a lack of well-dated records spanning earlier terminations. A notable exception to this is a suite of remarkably well-dated Chinese speleothems that have been used to date the commencement of each termination over the past 640 kyr [2,3]. This has been achieved by correlating weak Asian Monsoon anomalies as captured by speleothem oxygen isotope signals with terminal Heinrich events in the North Atlantic. While this approach is well-suited to testing orbital hypothesis by comparing the timing of termination commencement with insolation metrics, it only provides precise age control at the beginning of each termination. This precludes assessment of the progression of climatic changes over the full course of the termination, and the timing at which full interglacial conditions are reached. Here we present a composite speleothem record spanning glacial terminations IV and V from the Antro del Corchia cave system located on the western coast of central Italy. This record is anchored to a uranium-thorium based chronology and contains numerous proxies representing both local and regional climate, including Δ47-based temperature data derived from a pool carbonate formed under very slow degassing conditions. By taking advantage of established links between speleothem proxies from this cave site and marine proxies from the North Atlantic, we fix the marine sediment data to a radiometric age scale. This allows us to constrain the timing of ocean circulation and SST changes occurring in the North Atlantic throughout the duration of Terminations IV and V, and compare these with terrestrial temperatures in central Italy. © The Authors.