Browsing by Author "Francke, A"

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    The application of pollen radiocarbon dating and bayesian age-depth modeling for developing robust geochronological frameworks of wetland archives
    (Cambridge University Press for the Arizona Board of Regents on behalf of the University of Arizona, 2022-04-27) Cadd, H; Sherborne-Higgins, B; Becerra-Valdivia, L; Tibby, J; Barr, C; Forbes, MS; Cohen, TJ; Tyler, JJ; Vandergoes, MJ; Francke, A; Lewis, RJ; Jacobsen, GE; Marjo, CE; Turney, CSM; Arnold, LJ
    Wetland sediments are valuable archives of environmental change but can be challenging to date. Terrestrial macrofossils are often sparse, resulting in radiocarbon (14C) dating of less desirable organic fractions. An alternative approach for capturing changes in atmospheric 14C is the use of terrestrial microfossils. We 14C date pollen microfossils from two Australian wetland sediment sequences and compare these to ages from other sediment fractions (n = 56). For the Holocene Lake Werri Berri record, pollen 14C ages are consistent with 14C ages on bulk sediment and humic acids (n = 14), whilst Stable Polycyclic Aromatic Carbon (SPAC) 14C ages (n = 4) are significantly younger. For Welsby Lagoon, pollen concentrate 14C ages (n = 21) provide a stratigraphically coherent sequence back to 50 ka BP. 14C ages from humic acid and >100 µm fractions (n = 13) are inconsistent, and often substantially younger than pollen ages. Our comparison of Bayesian age-depth models, developed in Oxcal, Bacon and Undatable, highlight the strengths and weaknesses of the different programs for straightforward and more complex chrono-stratigraphic records. All models display broad similarities but differences in modeled age-uncertainty, particularly when age constraints are sparse. Intensive dating of wetland sequences improves the identification of outliers and generation of robust age models, regardless of program used. © The Author(s), 2022. Published by Cambridge University Press for the Arizona Board of Regents on behalf of the University of Arizona
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    Differentiating between the d13C signature from environmental conditions and SOM cycling in eastern Australian peat sediments
    (Australasian Quaternary Association (AQUA), 2021-07-08) Forbes, MS; Cohen, TJ; Marx, SK; Sherborne-Higgins, B; Cadd, H; Francke, A; Cendón, DI; Peterson, MA; Mooney, SD; Constantine, M; Boesl, F; Kobayashi, Y; Mazumder, D
    The analysis of stable carbon isotopes is commonly used in Quaternary science to reconstruct the environmental conditions and vegetation contributions to sedimentary sequences. However, the measured d13C signature of the total organic matter (OM) pool can also reflect other complexities within depositional environments. The peats of the Thirlmere Lakes system in the southern section of the Blue Mountains World Heritage Area provides an excellent opportunity to closely scrutinise such d13C dynamics. These deposits are rich in TOC (20-40%) meaning analytical techniques such as 13C-NMR, used to characterise the OM pool, can be applied effectively. Furthermore, the identification of several peat units deposited over the last ~130 ka allows for temporal comparisons. d13C values determined for a 7 m sediment sequence from Lake Couridjah representing both the MIS 1 and MIS 5e interglacial periods vary by up to 4 to 6‰. These trends were subsequently identified in two other sediment sequences (Lake Baraba and Lake Werri Berri) proximal to Lake Couridjah. Initially we interpreted our results as reflecting a C3 dominated vegetation environment with MIS 1 wetter than MIS 5e, following the established relationship between water stress and d13C enrichment. However, spectral analysis of the OM pool indicates that d13C is driven by changing OM dynamics rather than large changes in environmental conditions. In these environments, the greater presence of carbohydrates (i.e. cellulose) in MIS 1 result in more depleted d13C values. In contrast, the MIS 5e peat is dominated by relative inert OM C fractions including charcoal and lipids (such as leaf waxes), which influences environmental proxies such as C/N. Thus, it is likely that the older MIS 5e peat is a more decomposed version of the active MIS 1 peat, and thus differentiating environmental conditions between the two using d13C alone is not particularly illuminating. To overcome this, we describe the d13C values for a coarse charcoal and high temperature hydrogen pyrolysis fractions, modern vegetation, catchment POC and DOC, and n-alkanes composition and generate catchment carbon models for both MIS 1 and MIS5e. Finally comparing the size of the OM pools of both interglacial deposits can provide useful information in estimating the carbon storage capacity of peat deposits in eastern Australia over these time scales. © The Authors.
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    Differentiating between the d13C signature from environmental conditions and SOM cycling in eastern Australian peat sediments
    (Australasian Environmental Isotope Conference, 2022-11-14) Forbes, MS; Cohen, TJ; Marx, SK; Sherborne-Higgins, B; Cadd, H; Francke, A; Cendón, DI; Peterson, MA; Mooney, SD; Constantine, M; Boesl, F; Kobayashi, Y; Mazumder, D
    The analysis of stable carbon isotopes is commonly used in Quaternary science to reconstruct the environmental conditions and vegetation contributions to sedimentary sequences. However, the measured d13C signature of the total organic matter (OM) pool can also reflect other complexities within depositional environments. The peats of the Thirlmere Lakes system in the southern section of the Blue Mountains World Heritage Area provides an excellent opportunity to closely scrutinise such d13C dynamics. These deposits are rich in TOC (20-40%) meaning analytical techniques such as 13C-NMR, used to characterise the OM pool, can be applied effectively. Furthermore, the identification of several peat units deposited over the last ~130 ka allows for temporal comparisons. d13C values determined for a 7 m sediment sequence from Lake Couridjah representing both the MIS 1 and MIS 5e interglacial periods vary by up to 4 to 6‰. These trends were subsequently identified in two other sediment sequences (Lake Baraba and Lake Werri Berri) proximal to Lake Couridjah. Initially we interpreted our results as reflecting a C3 dominated vegetation environment with MIS 1 wetter than MIS 5e, following the established relationship between water stress and d13C enrichment. However, spectral analysis of the OM pool indicates that d13C is driven by changing OM dynamics rather than large changes in environmental conditions. In these environments, the greater presence of carbohydrates (i.e. cellulose) in MIS 1 result in more depleted d13C values. In contrast, the MIS 5e peat is dominated by relative inert OM C fractions including charcoal and lipids (such as leaf waxes), which influences environmental proxies such as C/N. Thus, it is likely that the older MIS 5e peat is a more decomposed version of the active MIS 1 peat, and thus differentiating environmental conditions between the two using d13C alone is not particularly illuminating. To overcome this, we describe the d13C values for a coarse charcoal and high temperature hydrogen pyrolysis fractions, modern vegetation, catchment POC and DOC, and n-alkanes composition and generate catchment carbon models for both MIS 1 and MIS5e. Finally comparing the size of the OM pools of both interglacial deposits can provide useful information in estimating the carbon storage capacity of peat deposits in eastern Australia over these time scales.
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    Fire and ecosystem change on Kangaroo Island, South Australia, over the past 5,000 years
    (2021-07-08) Duxbury, LC; Tyler, JJ; Ambrecht, LH; Francke, A; Cadd, HR; Law, WB; Zawadzki, A; Child, DP; Gadd, PS; Jacobsen, GE; Tibby, J; Mitchell, KJ
    Fire has long been a familiar and important part of Australian landscapes. However, anthropogenic climate change has heralded major shifts in fire regimes, negatively impacting ecosystems. These effects are expected to worsen in coming years, but there remain difficulties with projecting fire regime trajectories and their environmental impacts, in part due to a lack of data on centennial to millennial timescales. Uncertainties remain concerning the independent effects of climate and human impact on bushfires, and the long term impacts of fire on both terrestrial and aquatic ecosystems. This study aims to address these uncertainties by returning to Lashmars Lagoon, Kangaroo Island, a site of pioneering palaeoenvironmental research in South Australia. Kangaroo Island presents a fascinating case study, due to the putative abandonment of the island by ancient Aboriginal populations 2,450 ± 300 cal yrs BP. As such, it represents a unique opportunity to study the impact of cessation of Aboriginal management practices on ecosystems prior to European invasion. We collected sediment cores from Lashmars Lagoon, which we estimate to span the past 5,000 years. We are combining multiple palaeoecological and geochemical proxies to infer both fire and hydroclimate variability, augmented by an age model based on Pb-210, Pu isotopic profiling and C-14 dating. We will also analyse sedimentary ancient DNA (sedaDNA), which we hope will provide novel insights into the occurrence of taxa not usually detected through conventional palaeoecology. Our aim is to provide insights into the drivers of palaeofire and ecosystem response to changing fire regimes, with relevance to contemporary bushfire predictability and environmental management. For this conference, we will present preliminary data with a particular focus on the recent historical period. The potential and challenges of using lake sedaDNA in an Australian context will also be discussed. © The Authors.
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    Holocene climate, fire and ecosystem change on Kangaroo Island, South Australia
    (Australian Nuclear Science and Technology Organisation, 2021-11-17) Duxbury, LC; Tyler, JJ; Armbrecht, L; Francke, A; Cadd, H; Law, WB; Zawadzki, A; Child, DP; Gadd, PS; Jacobsen, GE; Tibby, J; Mitchell, K
    Introduction Fire has long been a familiar and important part of Australian landscapes. However, anthropogenic climate change has heralded major shifts in fire regimes, negatively impacting ecosystems. These effects are expected to worsen in coming years, but there remain difficulties with projecting fire regime trajectories and their environmental impacts, in part due to a lack of data on centennial to millennial timescales. Uncertainties remain concerning the independent effects of climate and human impact on bushfires, and the long term impacts of fire on both terrestrial and aquatic ecosystems. Aims This study aims to address these uncertainties by returning to Lashmars Lagoon, Kangaroo Island, a site of pioneering palaeoenvironmental research in South Australia that has been overlooked in recent decades. Kangaroo Island presents a fascinating case study, due to the putative abandonment of the island by ancient Aboriginal populations ~ 2,500 years ago. As such, it represents a unique opportunity to study the impact of cessation of Aboriginal management practices on ecosystems prior to European invasion. Methods We collected a ~ 7.5 metre long sediment core from Lashmars Lagoon, which we expected, from the work of previous studies, to span the past 5,000 years. We are combining multiple traditional and novel palaeoecological and geochemical proxies to infer both fire, catchment and ecosystem variability, augmented by an age model based on Pb-210, Pu isotopic profiling and C-14 dating. Results Our preliminary age model determined our core to span the past ~ 7,000 years, an adjustment to previous estimates. Our model is based on the radiocarbon dating of 6 plant macrofossils, 2 pollen samples and 1 shell. The pollen dates concur well with the plant macrofossils. The shell demonstrates an older age than the other samples from a similar horizon, a 'reservoir effect' that is expected from the integration of older carbon into the sample. The model also integrates 15 Pb-210 dates from the uppermost 30 cm, verified by the establishment of a nuclear bomb testing peak from Pu isotopic profiling. The broad peak detected in the Pu profile is also worthwhile of mention. Further interrogation of this phenomenon could be useful to infer certain processes the uppermost sediments, such as bioturbation, lateral leaching of Pu in the sediment or disturbance from the coring process. Overall, the age model indicates a constant rate of sedimentation approximately 1 mm/yr across the entire length of the, a somewhat surprising result given the considerable variation in sedimentology. Conclusions The development of a robust age model is integral to the interpretation of environmental, geochemical and climatic proxies at Lashmars Lagoon, South Australia. Importantly, the better constraint of our age model improves certainty around the timing of the human exodus from Kangaroo Island and the resultant discontinuation of Indigenous fire management. © The Authors