Identification of bridged CO2 binding in a Prussian blue analogue using neutron powder diffraction

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Date
2013-01-01
Authors
Ogilvie, SH
Duyker, SG
Southon, PD
Peterson, VK
Kepert, CJ
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Abstract
Neutron powder diffraction measurements were carried out on the evacuated and CO2-loaded Prussian blue analogue, Fe3[Co(CN)6]2, identifying two distinct CO2 adsorption sites: site A, in which CO2 uniquely bridges between two bare-metal sites, and site B, in which it interacts in a face capping motif. The saturation of site A at low loadings of CO2 demonstrates the favourable nature of the interaction of CO2 with bare-metal sites within the material. © 2013, Royal Society of Chemistry.
Description
Keywords
Metals, Design, Carbon dioxide, Adsorption, Neutron diffraction, Neutrons
Citation
Ogilvie, S. H., Duyker, S. G., Southon, P. D., Peterson, V. K., & Kepert, C. J. (2013). Identification of bridged CO2 binding in a Prussian blue analogue using neutron powder diffraction. Chemical Communications, 49(82), 9404-9406. doi:10.1039/c3cc46019c
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