Identification of bridged CO2 binding in a Prussian blue analogue using neutron powder diffraction

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dc.contributor.authorOgilvie, SHen_AU
dc.contributor.authorDuyker, SGen_AU
dc.contributor.authorSouthon, PDen_AU
dc.contributor.authorPeterson, VKen_AU
dc.contributor.authorKepert, CJen_AU
dc.date.accessioned2014-06-20T04:30:16Zen_AU
dc.date.available2014-06-20T04:30:16Zen_AU
dc.date.issued2013-01-01en_AU
dc.date.statistics2014-06-20en_AU
dc.description.abstractNeutron powder diffraction measurements were carried out on the evacuated and CO2-loaded Prussian blue analogue, Fe3[Co(CN)6]2, identifying two distinct CO2 adsorption sites: site A, in which CO2 uniquely bridges between two bare-metal sites, and site B, in which it interacts in a face capping motif. The saturation of site A at low loadings of CO2 demonstrates the favourable nature of the interaction of CO2 with bare-metal sites within the material. © 2013, Royal Society of Chemistry.en_AU
dc.identifier.citationOgilvie, S. H., Duyker, S. G., Southon, P. D., Peterson, V. K., & Kepert, C. J. (2013). Identification of bridged CO2 binding in a Prussian blue analogue using neutron powder diffraction. Chemical Communications, 49(82), 9404-9406. doi:10.1039/c3cc46019cen_AU
dc.identifier.govdoc5437en_AU
dc.identifier.issn1359-7345en_AU
dc.identifier.issue82en_AU
dc.identifier.journaltitleChemical Communicationsen_AU
dc.identifier.pagination9404-9406en_AU
dc.identifier.urihttp://dx.doi.org/10.1039/c3cc46019cen_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/5702en_AU
dc.identifier.volume49en_AU
dc.language.isoenen_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.subjectMetalsen_AU
dc.subjectDesignen_AU
dc.subjectCarbon dioxideen_AU
dc.subjectAdsorptionen_AU
dc.subjectNeutron diffractionen_AU
dc.subjectNeutronsen_AU
dc.titleIdentification of bridged CO2 binding in a Prussian blue analogue using neutron powder diffractionen_AU
dc.typeJournal Articleen_AU
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