A non-topological mechanism for negative linear compressibility

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dc.contributor.authorBinns, Jen_AU
dc.contributor.authorKamenev, KVen_AU
dc.contributor.authorMarriott, KERen_AU
dc.contributor.authorMcIntyre, GJen_AU
dc.contributor.authorMoggach, SAen_AU
dc.contributor.authorMurrie, Men_AU
dc.contributor.authorParsons, Sen_AU
dc.date.accessioned2021-12-17T03:19:02Zen_AU
dc.date.available2021-12-17T03:19:02Zen_AU
dc.date.issued2016-05-13en_AU
dc.date.statistics2021-12-07en_AU
dc.description.abstractNegative linear compressibility (NLC), the increase in a unit cell length with pressure, is a rare phenomenon in which hydrostatic compression of a structure promotes expansion along one dimension. It is usually a consequence of crystal structure topology. We show that the source of NLC in the Co(II) citrate metal–organic framework UTSA-16 lies not in framework topology, but in the relative torsional flexibility of Co(II)-centred tetrahedra compared to more rigid octahedra.© Open Access CC BY Licence - The Royal Society of Chemistry 2016en_AU
dc.identifier.citationBinns, J., Kamenev, K. V., Marriott, K. E. R., McIntyre, G. J., Moggach, S. A., Murrie, M., & Parsons, S. (2016). A non-topological mechanism for negative linear compressibility. Chemical Communications, 52(47), 7486-7489. doi:0.1039/C6CC02489Ken_AU
dc.identifier.issn1364-548Xen_AU
dc.identifier.issue47en_AU
dc.identifier.journaltitleChemical Communicationsen_AU
dc.identifier.pagination7486-7489en_AU
dc.identifier.urihttps://doi.org/10.1039/C6CC02489Ken_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/12543en_AU
dc.identifier.volume52en_AU
dc.language.isoenen_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.subjectHydrostaticsen_AU
dc.subjectCompressionen_AU
dc.subjectCompressibilityen_AU
dc.subjectCrystal structureen_AU
dc.subjectTopologyen_AU
dc.subjectFlexibilityen_AU
dc.titleA non-topological mechanism for negative linear compressibilityen_AU
dc.typeJournal Articleen_AU
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