Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator

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dc.contributor.authorMills, SJen_AU
dc.contributor.authorAishima, Jen_AU
dc.contributor.authorAragao, Den_AU
dc.contributor.authorCaradoc-Davies, TTen_AU
dc.contributor.authorCowieson, NPen_AU
dc.contributor.authorGee, CLen_AU
dc.contributor.authorEricsson, Den_AU
dc.contributor.authorHarrop, SJen_AU
dc.contributor.authorPanjikar, Sen_AU
dc.contributor.authorSmith, KMLen_AU
dc.contributor.authorRiboldi-Tunnicliffe, Aen_AU
dc.contributor.authorWilliamson, Ren_AU
dc.contributor.authorPrice, JRen_AU
dc.date.accessioned2023-12-21T01:30:06Zen_AU
dc.date.available2023-12-21T01:30:06Zen_AU
dc.date.issued2020-06-30T14:00:00Zen_AU
dc.date.statistics2023-06-21en_AU
dc.description.abstractExceptionally large crystals of posnjakite, CuSO(OH)(HO), formed during corrosion of a Swagelock(tm) Snubber copper gasket within the MX1 beamline at the ANSTO-Melbourne, Australian Synchrotron. The crystal structure was solved using synchrotron radiation to = 0.029 and revealed a structure based upon [Cu(OH)(HO)O] sheets, which contain Jahn-Teller-distorted Cu octa-hedra. The sulfate tetra-hedra are bonded to one side of the sheet corner sharing and linked to successive sheets extensive hydrogen bonds. The sulfate tetra-hedra are split and rotated, which enables additional hydrogen bonds. © Mills et al. 2020.en_AU
dc.description.sponsorshipThis research was undertaken in part using the MX1 beamline at the Australian Synchrotron, part of ANSTO.en_AU
dc.identifier.citationMills, S., Aishima, J., Aragao, D., Caradoc-Davies, T. T., Cowieson, N., Gee, C. L., Ericsson, D., Harrop, S., Panjikar, S., Smith, K. M. L., Riboldi-Tunnicliffe, A., Williamson, R., & Price, J. R. (2020). Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator. Acta Crystallographica. Section E, Crystallographic Communications, 76(7), 1136–1138. doi:10.1107/S2056989020008099en_AU
dc.identifier.issn2056-9890en_AU
dc.identifier.issue7en_AU
dc.identifier.journaltitleActa Crystallographica. Section E: Crystallographic Communicationsen_AU
dc.identifier.pagination1136–1138en_AU
dc.identifier.urihttps://apo.ansto.gov.au/handle/10238/15295en_AU
dc.identifier.volume76en_AU
dc.language.isoenen_AU
dc.publisherInternational Union of Crystallography (IUCr)en_AU
dc.relation.urihttps://doi.org/10.1107/S2056989020008099en_AU
dc.subjectCopperen_AU
dc.subjectCorrosionen_AU
dc.subjectHydrogenen_AU
dc.subjectEquipmenten_AU
dc.subjectFailuresen_AU
dc.subjectCrystal structureen_AU
dc.subjectANSTOen_AU
dc.subjectSynchrotronsen_AU
dc.subjectJahn-Teller effecten_AU
dc.subjectChemical bondsen_AU
dc.titleCrystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromatoren_AU
dc.typeJournal Articleen_AU
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