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Please use this identifier to cite or link to this item: http://apo.ansto.gov.au/dspace/handle/10238/3736

Title: Nanoscale condensation of water on self-assembled monolayers
Authors: James, M
Darwish, TA
Ciampi, S
Sylvester, SO
Zhang, Z
Ng, A
Gooding, JJ
Hanley, TL
Keywords: Water
Vapor Condensation
Neutron Reflectors
Atomic Force Microscopy
Layers
Molecular Structure
Issue Date: 7-Jun-2011
Publisher: ROYAL SOC CHEMISTRY
Citation: James, M., Darwish, T.A., Ciampi, S., Sylvester, S.O., Zhang, Z.M., Ng, A., Gooding, J.J., Hanley, T.L. (2011). Nanoscale condensation of water on self-assembled monolayers. Soft Matter, 7(11), 5309-5318.
Abstract: We demonstrate that water is almost universally present on apparently dry self-assembled monolayers, even on those considered almost hydrophobic by conventional methods such as water contact goniometry. The structure and kinetics of nanoscale water adsorption onto these surfaces were investigated using X-ray and neutron reflectometry, as well as atomic force microscopy. Condensation of water on hydrophilic surfaces under ambient conditions formed a dense sub-nanometre surface layer; the thickness of which increased with exponentially limiting kinetics. Tapping mode AFM measurements show the presence of nanosized droplets that covered a small percentage ([similar]2%) of the total surface area, and which became fewer in number and larger in size with time. While low vacuum pressures ([similar]10-8 bar) at room temperature did nothing to remove the adsorbed water from these monolayers, heating to temperatures above 65 [degree]C under atmospheric conditions did lead to evaporation from the surface. We demonstrate that water contact angle measurements are not necessarily sensitive to the presence of nanoscale adsorbed water and do not vary with time. For the most part they are a poor indicator of the kinetics and the amount of water condensation onto these surfaces at the molecular level. In summary, this study reveals the need to exclude air containing even trace amounts of water vapor from such surfaces when characterizing using techniques such as X-ray reflectometry.© 2011, Royal Society of Chemistry
URI: http://dx.doi.org/10.1039/c1sm05096f
http://apo.ansto.gov.au/dspace/handle/10238/3736
ISSN: 1744-683X
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