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Please use this identifier to cite or link to this item: http://apo.ansto.gov.au/dspace/handle/10238/3696

Title: A Spectroscopic Investigation of Magnetic Exchange Between Highly Anisotropic Spin Centers
Authors: Boeer, AB
Barra, AL
Chibotaru, LF
Collison, D
McInnes, EJL
Mole, RA
Simeoni, GG
Timco, GA
Ungur, L
Unruh, T
Winpenny, REP
Keywords: Cobalt
Inelastic Scattering
Spectroscopy
Anisoptropy
Spin
Molecules
Issue Date: 18-Apr-2011
Publisher: WILEY-BLACKWELL
Citation: Boeer, A.B., Barra, A.L., Chibotaru, L.F., Collison, D., McInnes, E.J.L., Mole, R.A., Simeoni, G.G., Timco, G.A., Ungur, L., Unruh, T., Winpenny, R.E.P., A Spectroscopic Investigation of Magnetic Exchange Between Highly Anisotropic Spin Centers. Angewandte Chemie-International Edition, 50(17), 4007-4011.
Abstract: Structurally similar, magnetically diverse: The exchange and Zeeman parameters of two dimetallic, six-coordinate cobalt(II) compounds—i.e., with orbitally degenerate metal ions—have been determined by a combination of high-resolution EPR and INS spectroscopies, together with ab intio calculations. It is suggested that the correlation between the local crystal field about the CoII centers and the superexchange pathway controls the magnetic interaction. © 2011, Wiley-Blackwell. The definitive version is available at www3.interscience.wiley.com
URI: http://dx.doi.org/10.1002/anie.201100306
http://apo.ansto.gov.au/dspace/handle/10238/3696
ISSN: 1433-7851
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