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Please use this identifier to cite or link to this item: http://apo.ansto.gov.au/dspace/handle/10238/3695

Title: A flexible copper based microporous metal-organic framework displaying selective adsorption of hydrogen over nitrogen
Authors: Nadeem, MA
Thornton, AW
Hill, MR
Stride, JA
Keywords: Hydrogen
Nitrogen
Ligand
Sorption
Molecular Dynamics Methods
Atoms
Issue Date: 1-Apr-2011
Publisher: Royal Society of Chemistry
Citation: Nadeem, M.A., Thornton, A.W., Hill, M.R., Stride, J.A. (2011). A flexible copper based microporous metal-organic framework displaying selective adsorption of hydrogen over nitrogen. Dalton Transactions, 40(13), 3398-3401.
Abstract: A microporous metal-organic framework [Cu-3(ipO)(2)(pyz)(2)](n), (ipO = 2-hydroxyisophthalic acid, pyz = pyrazine) was synthesized via an in situ. ligand transformation reaction. The microporous framework displays helical arrays of ipo ligands holding the Cu atoms in 2D sheets, whilst the coordination of pyz molecules acts to arrange these sheets into a microporous 3D structure. Remarkable selective sorption behaviour (>5) for H-2 over N-2 is observed and explained with molecular dynamics simulations.© 2011, Royal Society of Chemistry.
URI: http://dx.doi.org/10.1039/c0dt01531h
http://apo.ansto.gov.au/dspace/handle/10238/3695
ISSN: 1477-9226
Appears in Collections:Journal Articles

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