Repository logo


A flexible copper based microporous metal-organic framework displaying selective adsorption of hydrogen over nitrogen

Loading...
Thumbnail Image

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

A microporous metal-organic framework [Cu-3(ipO)(2)(pyz)(2)](n), (ipO = 2-hydroxyisophthalic acid, pyz = pyrazine) was synthesized via an in situ. ligand transformation reaction. The microporous framework displays helical arrays of ipo ligands holding the Cu atoms in 2D sheets, whilst the coordination of pyz molecules acts to arrange these sheets into a microporous 3D structure. Remarkable selective sorption behaviour (>5) for H-2 over N-2 is observed and explained with molecular dynamics simulations.© 2011, Royal Society of Chemistry.

Description

Citation

Nadeem, M.A., Thornton, A.W., Hill, M.R., Stride, J.A. (2011). A flexible copper based microporous metal-organic framework displaying selective adsorption of hydrogen over nitrogen. Dalton Transactions, 40(13), 3398-3401. doi:10.1039/c0dt01531h

Collections

Endorsement

Review

Supplemented By

Referenced By