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Please use this identifier to cite or link to this item: http://apo.ansto.gov.au/dspace/handle/10238/3557

Title: Composite polymer electrolyte containing ionic liquid and functionalized polyhedral oligomeric silsesquioxanes for anhydrous PEM applications.
Authors: Subianto, S
Mistry, MK
Choudhury, NR
Dutta, NK
Knott, R
Keywords: Fuel Cells
Ionic Composition
Liquids
Proton Conductivity
Mechanical Properties
Membranes
Issue Date: 24-Jun-2009
Publisher: American Chemical Society
Citation: Subianto, S., Mistry, M. K., Choudhury, N. R., Dutta, N. K., & Knott, R. (2009). Composite polymer electrolyte containing ionic liquid and functionalized polyhedral oligomeric silsesquioxanes for anhydrous PEM applications. ACS Applied Materials & Interfaces, 1(6), 1173-1182.
Abstract: A new type of supported liquid membrane was made by combining an ionic liquid (IL) with a Nafion membrane reinforced with multifunctional polyhedral oligomeric silsesquioxanes (POSSs) using a layer-by-layer strategy for anhydrous proton-exchange membrane (PEM) application. The POSS was functionalized by direct sulfonation, and the sulfonated POSS (S-POSS) was incorporated into Nafion 117 membranes by the infiltration method. The resultant hybrid membrane shows strong ionic interaction between the Nafion matrix and the multifunctional POSS, resulting in increased glass transition temperature and thermal stability at very low loadings of S-POSS (1%). The presence of S-POSS has also improved the proton conductivity especially at low humidities, where it shows a marked increase due to its confinement in the ionic domains and promotes water uptake by capillary condensation. In order to achieve anhydrous conductivity, the IL 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BMI-BTSI) was incorporated into these membranes to provide proton conduction in the absence of water. Although the incorporation of an IL shows a plasticizing effect on the Nafion membrane, the S-POSS composite membrane with an IL shows a higher modulus at high temperatures compared to Nafion 117 and a Nafion−IL membrane, with significantly higher proton conductivity (5 mS/cm at 150°C with 20% IL). This shows the ability of the multifunctional POSS and IL to work symbiotically to achieve the desirable proton conductivity and mechanical properties of such membranes by enhancing the ionic interaction within the material. © 2009, American Chemical Society
URI: http://dx.doi.org/10.1021/am900020w
http://apo.ansto.gov.au/dspace/handle/10238/3557
ISSN: 1944-8244
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