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| Title: | Enhanced reversible lithium storage in a nanosize silicon/graphene composite. |
| Authors: | Chou, SL Wang, JZ Choucair, M Liu, HK Stride, JA Dou, SX |
| Keywords: | Silicon Electric Batteries Lithium Ions Ionic Conductivity Composite Materials Electrodes |
| Issue Date: | Feb-2010 |
| Publisher: | Elsevier |
| Citation: | Chou, S. L., Wang, J. Z., Choucair, M., Liu, H. K., Stride, J. A., & Dou, S. X. (2010). Enhanced reversible lithium storage in a nanosize silicon/graphene composite. Electrochemistry Communications, 12(2), 303-306. |
| Abstract: | Si/graphene composite was prepared by simply mixing of commercially available nanosize Si and graphene. Electrochemical tests show that the Si/graphene composite maintains a capacity of 1168 mAh g−1 and an average coulombic efficiency of 93% up to 30 cycles. EIS indicates that the Si/graphene composite electrode has less than 50% of the charge-transfer resistance compared with nanosize Si electrode, evidencing the enhanced ionic conductivity of Si/graphene composite. The enhanced cycling stability is attributed to the fact that the Si/graphene composite can accommodate large volume charge of Si and maintain good electronic contact. © 2010, Elsevier Ltd. |
| URI: | http://dx.doi.org/10.1016/j.elecom.2009.12.024 http://apo.ansto.gov.au/dspace/handle/10238/3204 |
| ISSN: | 1388-2481 |
| Appears in Collections: | Journal Articles
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