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Please use this identifier to cite or link to this item: http://apo.ansto.gov.au/dspace/handle/10238/2919

Title: In situ diffraction study on decomposition of Ti2AlN at 1500–1800°C in vacuum.
Authors: Pang, WK
Low, IM
Kennedy, SJ
Smith, RI
Keywords: Neutron Diffraction
Decomposition
Dissociation
Aluminium
Phase Transformations
Scanning Electron Microscopy
Issue Date: 25-Nov-2010
Publisher: Elsevier
Citation: Pang, W. K., Low, I. M., Kennedy, S. J., & Smith, R. I. (2010). In situ diffraction study on decomposition of Ti2AlN at 1500–1800°C in vacuum. Materials Science and Engineering a-Structural Materials Properties Microstructure and Processing, 528(1), 137-142.
Abstract: The susceptibility of Ti2AlN to thermal dissociation at 1500–1800°C in high-vacuum has been studied using in situ neutron diffraction. Above 1500°C, Ti2AlN decomposed to TiNx primarily through the sublimation of aluminium (Al). The kinetics of isothermal phase decomposition at 1550°C was modelled using a modified Avrami equation. An Avrami exponent (n) of 0.338 was determined, indicative of the highly restricted out-diffusion of Al between the channels of Ti6N octahedra. The characteristics of thermal stability and phase transition in Ti2AlN are discussed. Characterisation of surface compositions and examination of cross-sectional microstructures of decomposed Ti2AlN, using synchrotron radiation diffraction and SEM, respectively, verify the findings of the neutron diffraction; that Ti2AlN decomposes to TiNx at the surface primarily via the sublimation of Al from grain boundaries. © 2010, Elsevier Ltd.
URI: http://dx.doi.org/10.1016/j.msea.2010.08.012
http://apo.ansto.gov.au/dspace/handle/10238/2919
ISSN: 0921-5093
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