ANSTO Publications Online: Reduction of a chelating bis(NHC) palladium(II) complex to [{μbis( NHC)}2Pd2H]+: a terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions.

Please use this identifier to cite or link to this item: http://apo.ansto.gov.au/dspace/handle/10238/2505

Title:	Reduction of a chelating bis(NHC) palladium(II) complex to [{μbis( NHC)}2Pd2H]+: a terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions.
Authors:	Boyd, PDW Edwards, AJ Gardiner, MG Ho, CC Lemee-Cailleau, MH McGuinness, DS Riapanitra, A Steed, JW Stringer, DN Yates, BF
Keywords:	Palladium Homogeneous Catalysis Coupling Carbenes Crystal Structure Reduction
Issue Date:	23-Aug-2010
Publisher:	Wiley-VCH Verlag Berlin
Citation:	Boyd, P. D. W., Edwards, A. J., Gardiner, M. G., Ho, C. C., Lemee-Cailleau, M. H., McGuinness, D. S., et al. (2010). Reduction of a chelating bis(NHC) palladium(II) complex to [{μbis( NHC)}2Pd2H]+: a terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions. Angewandte Chemie-International Edition, 49(36), 6315-6318.
Abstract:	The first palladium(I) N-heterocyclic carbene complex has been isolated in high yield by the base-assisted reduction of a palladium(II) precursor. The location of the unique terminal hydride (see picture; PdI cyan, H white, N blue) was established by neutron crystal structure determination, and the solution fluxional behavior of the complex was explored. © 2010, Wiley-VCH Verlag Berlin
URI:	http://dx.doi.org/10.1002/anie.201003177 http://apo.ansto.gov.au/dspace/handle/10238/2505
ISSN:	1433-7851
Appears in Collections:	Journal Articles

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