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|Title: ||Central atom size effect on the structure of group 14 tetratolyls.|
|Authors: ||Ng, MCC|
van Eijck, L
Molecular Dynamics Method
|Issue Date: ||6-Jul-2009|
|Publisher: ||Wiley-VCH Verlag Berlin|
|Citation: ||Ng, M. C. C., Craig, D. J., Harper, J. B., van Eijck, L., & Stride, J. A. (2009). Central atom size effect on the structure of group 14 tetratolyls. Chemistry-a European Journal, 15(27), 6569-6572.|
|Abstract: ||Size matters! The structure and dynamics of the tetratolyl Group 14 elements, which were probed by using high-resolution inelastic neutron scattering spectra, show a remarkable dependence on the size of the central atom. The para-methyl groups at the periphery of the molecules constitute the frontier intermolecular interactions of increasingly larger tetrahedra, which becomes critical at the molecular radius of the Si and Ge analogues. © 2009, Wiley-VCH Verlag Berlin|
|Appears in Collections:||Journal Articles|
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