ANSTO Publications Online: Central atom size effect on the structure of group 14 tetratolyls.

Please use this identifier to cite or link to this item: http://apo.ansto.gov.au/dspace/handle/10238/1872

Title:	Central atom size effect on the structure of group 14 tetratolyls.
Authors:	Ng, MCC Craig, DJ Harper, JB van Eijck, L Stride, JA
Keywords:	Crystallography Atoms Molecular Dynamics Method Inelastic Scattering Silicon Germanium
Issue Date:	6-Jul-2009
Publisher:	Wiley-VCH Verlag Berlin
Citation:	Ng, M. C. C., Craig, D. J., Harper, J. B., van Eijck, L., & Stride, J. A. (2009). Central atom size effect on the structure of group 14 tetratolyls. Chemistry-a European Journal, 15(27), 6569-6572.
Abstract:	Size matters! The structure and dynamics of the tetratolyl Group 14 elements, which were probed by using high-resolution inelastic neutron scattering spectra, show a remarkable dependence on the size of the central atom. The para-methyl groups at the periphery of the molecules constitute the frontier intermolecular interactions of increasingly larger tetrahedra, which becomes critical at the molecular radius of the Si and Ge analogues. © 2009, Wiley-VCH Verlag Berlin
URI:	http://dx.doi.org/10.1002/chem.200900360 http://apo.ansto.gov.au/dspace/handle/10238/1872
ISSN:	0947-6539
Appears in Collections:	Journal Articles

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