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Please use this identifier to cite or link to this item: http://apo.ansto.gov.au/dspace/handle/10238/1729

Title: Negative thermal expansion in the metal-organic framework material Cu-3(1,3,5-benzenetricarboxylate)(2).
Authors: Wu, Y
Kobayashi, A
Halder, GJ
Peterson, VK
Chapman, KW
Lock, N
Southon, PD
Kepert, CJ
Keywords: Thermal Expansion
Potassium Compounds
Ferrocyanides
Phase Transformations
Diffraction
Valence
Issue Date: 8-Aug-2008
Publisher: Wiley-VCH Verlag Berlin
Citation: Wu, Y., Kobayashi, A., Halder, G. J., Peterson, V. K., Chapman, K. W., Lock, N., et al. (2008). Negative thermal expansion in the metal-organic framework material Cu-3(1,3,5-benzenetricarboxylate)(2). Angewandte Chemie-International Edition, 47(46), 8929-8932.
Abstract: The metal–organic framework [Cu3(btc)2] displays negative thermal expansion (NTE) over a broad temperature range. This property arises from two coincident mechanisms, each of which are unique for NTE systems: the concerted transverse vibration of triangular organic linkers, and the local dynamic distortion of dinuclear metal centers within the framework lattice. © 2008, Wiley-VCH Verlag Berlin
URI: http://dx.doi.org/10.1002/anie.200803925
http://apo.ansto.gov.au/dspace/handle/10238/1729
ISSN: 1433-7851
Appears in Collections:Journal Articles

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