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|Title: ||Diffuse scattering and lattice dynamics of superionic copper chalcogenides.|
|Authors: ||Danilkin, SA|
|Keywords: ||Crystal Structure|
|Issue Date: ||14-May-2009|
|Citation: ||Danilkin, S. A. (2009). Diffuse scattering and lattice dynamics of superionic copper chalcogenides. Solid State Ionics, 180(6-8), 483-487.|
|Abstract: ||The energy-resolved neutron diffraction and inelastic neutron scattering study of diffuse scattering in copper chalcogenides was performed in order to clarify the role of static disorder versus low-energy phonons. Neutron diffraction patterns taken from Cu1.75Se, Cu1.98Se and Ag0.25Cu1.75Se powders in superionic phase show a broad maximum related to diffuse scattering. This diffuse background is suppressed in the energy-resolved experiment which indicates a strong contribution from inelastic scattering coming from correlated thermal displacements of the ions in the superionic phase. Diffraction experiments on a single crystal of α-Cu1.8Se have revealed an ordered structure with superstructure reflections at the G +/- 1/2 < 111 > and G +/- 1/3 < 220 > positions of reciprocal space at room temperature. In addition to superstructure spots, diffuse scattering was observed along the < 111 > direction which is considered as a possible diffusion path of mobile Cu ions. In inelastic neutron scattering measurements with this single crystal sample strong inelastic scattering was observed along < 111 >. This shows that the diffuse scattering found in conventional diffraction experiment is mainly inelastic and most probably comes from low-energy phonons. © 2009, Elsevier Ltd.|
|Appears in Collections:||Journal Articles|
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