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Please use this identifier to cite or link to this item: http://apo.ansto.gov.au/dspace/handle/10238/1381

Title: Structural and conductivity evolution of fluorite-type Bi2O3-Er2O3-PbO solid electrolytes during long-term annealing.
Authors: Webster, NAS
Ling, CD
Raston, CL
Lincoln, FJ
Keywords: Annealing
Electrolytes
Crystal Structure
Sintered Materials
Thermal Conductivity
Fluorite
Issue Date: Aug-2008
Publisher: Elsevier
Citation: Webster, N. A. S., Ling, C. D., Raston, C. L., & Lincoln, F. J. (2008). Structural and conductivity evolution of fluorite-type Bi2O3-Er2O3-PbO solid electrolytes during long-term annealing. Solid State Ionics, 179(19-20), 697-705.
Abstract: Quenched-in fcc fluorite-type materials in the Bi2O3-Er2O3-PbO system were annealed in air at 500 and 600 degrees C for up to 2000 h. Each material experienced a conductivity-lowering structural transformation, thus making them unsuitable for use in SOFCs. For example, the materials (BiO1.5)(0.80)(ErO1.5)(0.20-x)(PbO)(x), x = 0.03, 0.06 and 0.09, underwent a fluorite-type to tetragonal transformation during annealing at 500 degrees C due to (100) oxide-ion vacancy ordering, and the rate of conductivity decay at 500 degrees C increased with increasing Pb2+/Er3+ ratio. © 2008, Elsevier Ltd.
URI: http://dx.doi.org/10.1016/j.ssi.2008.04.016
http://apo.ansto.gov.au/dspace/handle/10238/1381
ISSN: 0167-2738
Appears in Collections:Journal Articles

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