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| Title: | Surface electronic properties of ZnO nanoparticles. |
| Authors: | Ton-That, C Phillips, MR Foley, M Moody, SJ Stampfl, APJ |
| Keywords: | Photoelectron Spectroscopy Absorption Oxygen Emission Photoemission Zinc Oxides |
| Issue Date: | 30-Jun-2008 |
| Publisher: | American Institute of Physics |
| Citation: | Ton-That, C., Phillips, M. R., Foley, M., Moody, S. J., & Stampfl, A. P. J. (2008). Surface electronic properties of ZnO nanoparticles. Applied Physics Letters, 92(26), 3. |
| Abstract: | The surface electronic structure of ZnO nanoparticles has been studied with photoemission and x-ray absorption spectroscopies. Contrary to expectation, ZnO:Zn phosphor nanoparticles were found to contain a lower oxygen vacancy density on the surface than undoped ZnO counterparts, but oxygen vacancies are in different chemical environments. Cathodoluminescence shows intense green luminescence from the ZnO:Zn surface, while the undoped nanoparticles exhibit only the near-band-edge emission. The results indicate the roles of surface oxygen vacancies and their environment in the previously unexplained green luminescence from the ZnO:Zn material. © 2008, American Institute of Physics |
| URI: | http://dx.doi.org/10.1063/1.2952955 http://apo.ansto.gov.au/dspace/handle/10238/1310 |
| ISSN: | 0003-6951 |
| Appears in Collections: | Journal Articles
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