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Title: Inelastic neutron scattering of H-2 adsorbed in HKUST-1.
Authors: Liu, Y
Brown, CM
Neumann, DA
Peterson, VK
Kepert, CJ
Keywords: Energy Storage
Hydrogen Storage
Sigma Model
Inelastic Scattering
Issue Date: 31-Oct-2007
Publisher: Elsevier
Citation: Liu, Y., Brown, C. M., Neumann, D. A., Peterson, V. K., & Kepert, C. J. (2007). Inelastic neutron scattering of H-2 adsorbed in HKUST-1. Journal of Alloys and Compounds, 446, 385-388.
Abstract: A series of inelastic neutron scattering (INS) investigations of hydrogen adsorbed in activated HKUST-1 (Cu-3(1,3,5-benzenetricarboxylate)(2)) result in INS spectra with rich features, even at very low loading (< 1.0 H-2:Cu). The distinct inelastic features in the spectra show that there are three binding sites that are progressively populated when the H-2 loading is less than 2.0 H-2:Cu, which is consistent with the result obtained from previous neutron powder diffraction experiments. The temperature dependence of the INS spectra reveals the relative binding enthalpies for H-2 at each site. © 2007, Elsevier Ltd.
ISSN: 0925-8388
Appears in Collections:Journal Articles

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