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Please use this identifier to cite or link to this item: http://apo.ansto.gov.au/dspace/handle/10238/1091

Title: Using XANES to monitor the oxidation state of cobalt complexes.
Authors: Hall, MD
Underwood, CK
Failes, TW
Foran, GJ
Hambley, TW
Keywords: Absorption
Salts
Antimitotic Drugs
Spectroscopy
Oxidation
Cysteine
Issue Date: 14-Feb-2007
Publisher: CSIRO Publishing
Citation: Hall, M. D., Underwood, C. K., Failes, T. W., Foran, G. J., & Hambley, T. W. (2007). Using XANES to monitor the oxidation state of cobalt complexes. Australian Journal of Chemistry, 60(3), 180-183.
Abstract: X-Ray absorption near-edge structure (XANES) spectroscopy was used to monitor the oxidation state of cobalt following treatment of Co-III complexes with reducing agents such as ascorbate and cysteine. It was established that the XANES spectra of mixtures of Co-II and Co-III complexes can be used to calculate proportions of the two oxidation states by monitoring the height of the Co K-edge. The relationships developed were used to estimate proportions of each complex in solutions of Co-III complexes treated with reducing agents. © 2007, CSIRO Publishing
URI: http://dx.doi.org/10.1071/CH06307
http://apo.ansto.gov.au/dspace/handle/10238/1091
ISSN: 0004-9425
Appears in Collections:Journal Articles

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