Supplementary Table 1 Number of locations Number of repeats 260 2 227 3 51 4 14 5 17 6 8 7 8 8 11 9 4 10 1 13 Number of locations with repeat sample collection and analysis through time in the dataset Supplementary Table 2 Depth Number of repeats SD- δ18O ‰ SD- δ2H  ‰     Mean Median 5th percentile 95th percentile Mean Median 5th percentile 95th percentile 1-30m 213 0.28 0.01 0.01 1.08 2.02 1.02 0.14 6.83 30-50m 132 0.2 0.1 0 0.71 1.27 0.78 0.1 4.75 50-300m 247 0.16 0.1 0.01 0.51 0.86 0.56 0.07 2.1 300-1000m 9 0.08 0.07 0.01 0.14 0.52 0.42 0.14 1.06 Mean, median, 5th and 95th percentiles of standard deviation by depth intervals for all repeated sites during sampling. Supplementary Table 3 Data Reference Apps, H.E., Halas, L., Schoning, G., Spulak, R., Halas, V., Gow, L., Magee, J., Somerville, P., Clarke, J.D.A., Lawrie, K.C., Brodie, R.S., Gibson, D., Christensen, N.B., Smith, M., Lymburner, L., McIntyre, A., Abraham, J., Brodie, R.C., Atkinson, I., Jaycock, J., Boston, K., Long, R., Rousseau, J., Maher, P., Davies, A., Ley-Cooper, Y. (2012). Broken Hill Managed Aquifer Recharge (BHMAR) Project: Securing Broken Hill's Water Supply: Assessment of Conjunctive Water Supply Options Involving Managed Aquifer Recharge and/or Groundwater Extraction at Menindee Lakes: Appendices. Record 2012/016. Geoscience Australia, Canberra. https://pid.geoscience.gov.au/dataset/ga/73824 Baird, D., 2001. Investigating River Water Loss and Aqifer Recharge at Narromine, NSW, using an Integrated Approach of Geophysics, Hydrogeochemistry and Environmental Isotopes. Hons. thesis, 224 pp. University of New South Wales. Banks, E. W., Hatch, M., Smith, S., Underschultz, J., Lamontagne, S., Suckow, A. and Mallants, D., 2019. Multi-tracer and hydrogeophysical investigation of the hydraulic connectivity between coal seam gas formations, shallow groundwater and stream network in a faulted sedimentary basin. Journal of Hydrology 578, 124132. https://doi.org/10.1016/j.jhydrol.2019.124132 Bartrop, E., 2014. Analysis of water level and water quality trends within shallow groundwater systems of monitoring sites within the Southern Sydney Basin's Camden Gas Project . Hons thesis. University of Wollongong. https://hdl.handle.net/10779/uow.27669954.v1. Budd, K.L., Plazinska, A.J. and Brodie, R.S., 2000. A groundwater quality assessment of the fractured basalt aquifers on the Alstonville Plateau, NSW. Bureau of Rural Sciences, Canberra. Caritat, P. de, Kirste, D., Dann, R., Evans, T., Schroder, I. and Main, P., 2022. Broken Hill Groundwater and Regolith Geochemistry (1999-2005): Datasets, Metadata and Geochemical Atlases. Record 2022/20. Geoscience Australia, Canberra. https://dx.doi.org/10.11636/Record.2022.020 Cartwright, I., Weaver, T. R., Cendón, D. I. and Swane, I., 2010. Environmental isotopes as indicators of inter-aquifer mixing, Wimmera region, Murray Basin, Southeast Australia. Chem. Geol. 277, 214-226. https://doi.org/10.1016/j.chemgeo.2010.08.002 Cartwright, I., Weaver, T. R., Cendón, D. I., Fifield, L. K., Tweed, S. O.Cartwright, I., Weaver, T. R., Cendón, D. I., Fifield, L. K., Tweed, S. O., Petrides, B. and Swane, I., 2012. Constraining groundwater flow, residence times, inter-aquifer mixing, and aquifer properties using environmental isotopes in the southeast Murray Basin, Australia. Applied Geochemistry 27, 1698-1709. https://doi.org/10.1016/j.apgeochem.2012.02.006 Cartwright I., Weaver T. R., Simmons C. T., Fifield L. K., Lawrence C. R., Chisari R. and Varley S., 2010. Physical hydrogeology and environmental isotopes to constrain the age, origins, and stability of a low-salinity groundwater lens formed by periodic river recharge: Murray Basin, Australia. Journal of Hydrology 380, 203-221. https://doi.org/10.1016/j.jhydrol.2009.11.001 Cartwright, I., Weaver, T. R., Stone, D. J. M. and Reid, M., 2007. Constraining modern and historical recharge from bore hydrographs, 3H, 14C, and chloride concentrations: Applications to dual-porosity aquifers in dryland salinity areas, Murray Basin, Australia. Journal of Hydrology 332, 69-92. https://doi.org/10.1016/j.jhydrol.2006.06.034 Cendón, D.I. and Hankin, S, 2008. 14C Ages for groundwater in the Bangalow and Ourimbah Creek borefields Gosford, NSW. Report ANSTO/C988 prepared for Gosford-Wyong City Council. Cendón, D.I. and Hankin, S. 2009. 14C Ages for groundwater in the Narara borefield Gosford, NSW. Report ANSTO/C1027 prepared for Gosford-Wyong City Council. Cendón, D.I., Hankin, S.I., Williams, J.P., van der Ley, M., Peterson, M., Hughes, C.E., Meredith, K., Graham, I.T., Hollins, S.E., Levchencko, V. and Chisari, R., 2014. Groundwater residence time in a dissected and weathered sandstone plateau: Kulnura–Mangrove Mountain aquifer, NSW, Australia. Australian Journal of Earth Sciences. http://dx.doi.org/10.1080/08120099.2014.893628 Cook, P. G.  and CSIRO. Land and Water, 2001. Groundwater recharge and discharge in a saline, urban catchment; Wagga Wagga, New South Wales. [Canberra] Cook, S., 2018. A multifaceted evaluation of hydraulic connectivity in heterogenous alluvium.Ph.D. thesis. University of New South Wales. https://doi.org/10.26190/unsworks/20350 Coram, J., 1999. Groundwater recharge in the Mooki River catchment, northern New South Wales, Draft Report. Australian Bureau of Rural Sciences, Land and Water Sciences Division. Denaro, D. 2011. Hawkesbury Sandstone Hosting Aquifers in the Lower Blue Mountains - An Analysis into Migrating Groundwaters and Host-Rock Interactions. Hons. thesis. University of New South Wales. Fisher, E.M., 2003. An investigation of salt mobilisation potential at Shepparton, Victoria, using an integrated approach of geophysics, electrokinetics, and hydrogeochemistry. Hons. thesis. University of Wollongong. Golder Associates Pty Ltd, 2021. Great Artesian Basin Springs Conceptualisation in NSW Report 21452652-001-R Rev0, prepared for NSW DPIE, Aug 2021, 168pp. Gray, D. and Bardwell N., 2016. Hydrogeochemistry of New South Wales: Data Release. v1. CSIRO. Data Collection. https://doi.org/10.4225/08/5756B395C68B0 Habermehl, M. A., Devonshire, J. and Magee, J. W., 2009. Sustainable Groundwater Allocations in the Intake Beds of the Great Artesian Basin in New South Wales: Final Report. Bureau of Rural Sciences, Canberra, March 2009. Hankin, S., Cendón, D.I., Harris, S., Dimovski, C., Kelly, B.F.J., 2022. Quantifying the N-cycle: hydrochemistry and isotopes of shallow groundwater in the Lower Namoi Alluvium. Report ANSTO/C1808 prepared for Cotton Research and Development Corporation. Harris, S.J., Cendón, D.I., Hankin, S., Peterson, M.A., Shuang Xiao, Dimovski, C., Kelly, B.F.J., 2022. Quantifying the N-cycle: hydrochemistry and isotopes of groundwater in the Lower Murrumbidgee Catchment. ANSTO/C1819, prepared for the Cotton Research and Development Corporation, September 2022, 77 pp. Herczeg. L.A., 2004. Groundwater ages, sources of salt and recharge mechanisms in the Lower Balonne area, Southern Queensland, Australia: Isotope and Geochemical data. CRCLEME Report 164, 28 pp. http://hdl.handle.net/102.100.100/184045?index=1 Heywood, J.E., 2003. A hydrochemical investigation into Urban Salinity at Badgerys Creek and Glenmore Park. Hons. thesis, 121 pp. University of Wollongong. Hollins, S., Meredith, K. and Twining, J., 2009. Study of groundwater-surface water interactions in the Macquarie Marshes and sources of water for riparian vegetation transpiration. ANSTO report prepared for NSW Department of Environment and Climate Change. Iverach, C., Cendón, D.I., Hankin, S., Harris, S., Kelly, B.F.J., 2019. Hydrogeochemical, Microbial and Isotopic Composition of Groundwater from the Lower Namoi Alluvial Aquifer between Narrabri and Wee Waa (NSW) – Implications for Groundwater Management. Report ANSTO/C1512 prepared for Cotton Research and Development Corporation. Jasonsmith, J., 2010. Origins of salinity and salinisation processes in the Wybong Creek Catchment, New South Wales, Australia. Ph.D. thesis, 310 pp. Australian National University. https://doi.org/10.25911/5d7a27fd2f5c4 Lavitt, N., 1999. Integrated approach to geology, hydrogeology and hydrogeochemistry in the Lower Mooki River Catchment, New South Wales, Australia. Ph.D. thesis. University of New South Wales. https://doi.org/10.26190/unsworks/12682 Lawrie, K.C., Brodie, R.S., Tan, K.P., Gibson, D., Magee, J., Clarke, J.D.A., Halas, L., Gow, L., Somerville, P., Apps, H.E., Smith, M., Christensen, N.B., Abraham, J., Hostetler, S. and Brodie, R.C., 2012. Broken Hill Managed Aquifer Recharge (BHMAR) Project: Securing Broken Hill's Water Supply: Assessment of Conjunctive Water Supply Options Involving Managed Aquifer Recharge and/or Groundwater Extraction at Menindee Lakes: Geological and Hydrogeological Framework and Conceptual Model. Record 2012/012. Geoscience Australia, Canberra. https://pid.geoscience.gov.au/dataset/ga/73820 Lenahan, M. J., 2007. The hydrogeochemistry of a saline aquifer system : central New South Wales, Australia. Ph.D. thesis. Australian National University. https://doi.org/10.25911/5d63c46fb8c82 Luu, E., 2009. Hawkesbury Sandstone Aquifers of the Sydney Basin- Potential Water-Rock Interactions on 14C Groundwater Dating. Hons. Thesis, University of NSW. McDonald, J.G. W., 2014. Hydrochemical processes in the Lower Murrumbidgee Area, NSW : the influence of weathering reactions, evaporation, and salt dissolution on groundwater quality. M.Phil. thesis, 190 pp. Australian National University. https://doi.org/10.25911/5d6120d90d252. McDonough, L.K., Rutlidge, H., O'Carroll, D.M., Andersen, M.S., Meredith, K., Behnke, M.I., Spencer, R.G.M., McKenna, A.M., Marjo, C.E., Oudone, P., Baker, A., 2020. Characterisation of shallow groundwater dissolved organic matter in aeolian, alluvial and fractured rock aquifers. Geochimica et Cosmochimica Acta 273, 163-176. doi.org/https://doi.org/10.1016/j.gca.2020.01.022. McLean, W., 2003. Hydrogeochemical evolution and variability in a stressed alluvial aquifer system: Lower Namoi River catchment, NSW. Ph.D. Thesis, University of New South Wales. https://doi.org/10.26190/unsworks/4465 Morgan, K., 2005. Evaluation of salinisation processes in the Spicers Creek catchment, central west region of New South Wales, Australia. Ph.D. Thesis, 350 pp. University of New South Wales. https://doi.org/10.26190/unsworks/23667 Parsons Brinckerhoff, 2006. Hydrochemical and environmental isotope sampling program - Upper Nepean groundwater investigation sites. 97 pp. Report prepared for Sydney Catchment Authority. Parsons Brinckerhoff, 2010. Broke Groundwater investigation and monitoring report (AGL Hunter Gas Project), 394 pp. Report prepared for AGL Energy Ltd. Parsons Brinckerhoff, 2014. Drilling Completion Report - Denham Court, Menangle Park and Glenlee. Report # 2114759B-WAT-RPT-7763 RevC, 27 Nov 2014 prepared for AGL Energy Ltd. Peterson, M.A., Cendón, D. I., Hankin, S. I, Chisari, R., 2012. Peabody: Metropolitan Colliery groundwater dating & chemistry. ANSTO/C1296, prepared for Peabody Energy Pty Ltd, Dec 2012, 84 pp. Please, P. M., 2000. A Groundwater quality assessment of the alluvial aquifers in the Border Rivers Catchment (Qld/NSW). Bureau of Rural Sciences, Canberra. https://collection.sl.nsw.gov.au/record/74VvoyM8d48b Pritchard, S. and Russell, G., 2000. Araluen Groundwater Study Water Quality Sampling Report, Department of Land and Water Conservation, Hydrogeology Unit, Wollongong. Radke, B.M., Ferguson, J., Creswell, R.G., Ransley, T.R., and Habermehl, M.A., 2000. Hydrochemistry and implied hydrodynamics of the Cadna-owie - Hooray Aquifer, Great Artesian Basin, Australia. Bureau of Rural Sciences, Canberra. Reid, N., Schroder, I., Thorne, R., Pinchand, T., Folkes, C., Eastlake, M., Hore, S., Petts, A., and Henne, A., 2024. Enhanced Mundi Hydrogeochemsitry - Data Release. v1. CSIRO. Data Collection. https://doi.org/10.25919/31rm-6h49 Reid, N., Thorne, R., Folkes, C., and Pinchand, T., 2024. Hydrogeochemistry of the Cobar Region - data release. v1. CSIRO. Data Collection. https://doi.org/10.25919/4673-f115 Rumpf, C., Thompson, J., Coleman, D., Bowen, S., Haeusler, T., 2021. Hydrogeology and ecology survey of the Great Artesian Basin springs in NSW: Survey methodology and results – NSW Department of Planning, Industry and Environment. 120 pp Rumpf, C., Thompson, J., Kumar, P., Gray S., 2021. Groundwater resource description for Macleay coastal sands. Report DOC21/201939. NSW Department of Planning, Industry and Environment, 71 pp. Rutlidge, H., McDonough, L.K., Oudone, P., Andersen, M.S., Meredith, K., Chinu, K., Peterson, M., Baker, A., 2021. Characterisation of groundwater dissolved organic matter using LCOCD: Implications for water treatment. Water Research 188, 116422. doi.org/https://doi.org/10.1016/j.watres.2020.116422. Schofield, S.K., 1998. The geology, hydrogeology and hydrogeochemistry of the Ballimore Region central New South Wales. Ph.D. Thesis, 715 pp. University of New South Wales. https://doi.org/10.26190/unsworks/14505 Shekarforoush, S., 1999. Groundwater chemistry and hydrogeochemical processes in fractured bedrock aquifers beneath dryland salinity occurences in SE Australia. Ph.D. thesis. University of New South Wales. Short, M., McPhail, D. and Hollins. S., 2014. Constraining hydrochemical pathways in a small internally draining basin (Lake George Basin, NSW) using isotopes of the water molecule, 22nd Australian Geological Convention (AESC 2014), Newcastle. Smithson, A. and Acworth, R.I., 2005. An Investigation of unconsolidated sedimentary units and their role in the development of salinity in the Snake Gully Catchment, Central New South Wales. Water Research Laboratory Research Report No 214, 124 pp. University of New South Wales. https://doi.org/10.26190/unsworks/363 Somerville P. D., 2010. Streamwater-groundwater interactions and implications for water sharing plans in unregulated catchments : Hunter Valley, eastern Australia. Ph.D. thesis. Australian National University. https://doi.org/10.25911/5d5fcc0ce1fd1 Taylor, S., 2016. The hydrogeochemistry of shallow groundwater in Western Sydney: a study of salinisation processes in shallow groundwater. Ph.D. thesis. University of Sydney. http://hdl.handle.net/2123/16115 Thomas, M., 2000. A hydrochemical and isotopic study of the water resources in the Bega Valley to assess the sustainable use of this resource. Hons. thesis, 102 pp. University of Wollongong. Timms, W.A. (2001). The importance of aquitard windows in the development of alluvial groundwater systems : Lower Murrumbidgee, Australia. Ph.D. thesis. University of New South Wales. https://doi.org/10.26190/unsworks/20687 Timms, W.A. and Acworth, R., 2002. Induced leakage due to groundwater pumping and flood irrigation at the Pullaming Agricultural Field Station, Liverpool Plains. Water Research Laboratory Report No 208. University of New South Wales https://www.connectedwaters.unsw.edu.au/sites/all/files/timms_acworth_2002_wrl-r208-pumping-leakage-pullaming.pdf. Walsh, C., Buckerfield, S., Raiber, M., Suckow, A., 2024. Upper Darling Floodplain hydrochemistry data. Geoscience Australia, Canberra. https://dx.doi.org/10.26186/149472 Watkins, K. L.,  Bauld, J., and Australia Bureau of Rural Science,  1999.  A groundwater quality assessment of shallow aquifers in the Murray Region, NSW. Bureau of Rural Sciences,  Canberra. Supplementary Figure 1 Supplementary Figure 2 Supplementary Figure 2. Semi-variograms (i.e. variance against distance) of sample δ18O data for the four depth intervals with optimised semi-variogram model fit. Supplementary Figure 3 Supplementary Figure 3 . δ2H isoscapes for the four depth intervals described in the main text. Cells depicted in white indicate no information available in the current layer. Cells depicted in grey correspond to those with information available in a different depth interval. Supplementary Figure 4 Supplementary Figure 8 . NSW river catchment locations. image1.png image2.png image3.png image4.png image5.png image6.png image7.png