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|Title:||Mössbauer study of the temperature dependence of electron delocalization in mixed valence freudenbergite|
|Publisher:||John Wiley & Sons, Inc.|
|Citation:||Cashion, J. D., Vance, E. R., & Ryan, D. H. (2020). Mössbauer study of the temperature dependence of electron delocalization in mixed valence freudenbergite. Journal of the American Ceramic Society, 103(10), 5496-5501. doi:10.1111/jace.17190|
|Abstract:||The evolution of the electron delocalization in the ferrous subspectra in a sample of mixed valence ferrous‐ferric freudenbergite has been followed by Mössbauer spectroscopy from 6 K to 650 K. The spectral changes do not involve the ferric component, leading to the conclusion that it is due to a thermally driven delocalization of the sixth d‐electron on the ferrous ions. The phenomenon does not occur in samples of pure ferrous freudenbergite. © 1999-2020 John Wiley & Sons, Inc.|
|Gov't Doc #:||9990|
|Appears in Collections:||Journal Articles|
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