Please use this identifier to cite or link to this item:
|Title:||Structural Characterization of Olivine Li (Mg0.5Ni0.5) PO4 by TEM|
Transmission electron microscopy
|Citation:||Minakshi, M., Singh, P., Ralph, D., Appadoo, D., Blackford, M., & Ionescu, M. (2012). Structural characteristics of olivine Li(Mg0.5Ni0.5)PO4 via TEM analysis. Ionics 18, 583–590. doi:10.1007/s11581-011-0661-0|
|Abstract:||The structural characteristics of olivine-type lithium orthophosphate Li(Mg0.5Ni0.5)PO4 synthesized via solid-state reaction have been studied using X-ray diffraction, ion beam technique, scanning electron microscopy, infrared spectroscopy, transmission electron microscopy and energy dispersive X-ray analysis. The parent LiNiPO4 compound can be synthesized in olivine structure without any evidence of secondary phases as impurities. The structural quality of the parent LiNiPO4 in the absence of secondary component phases resulted in the formation of hexagonal closed packed structure. The olivine analogue compound containing mixed M (M = Mg, Ni) cations, Li(Mg0.5Ni0.5)PO4 contained Li3PO4 as a second phase upon synthesis, however a carbothermal reduction method produced a single-phase compound. The redox behaviour of carbon-coated Li(Mg0.5Ni0.5)PO4 cathode in aqueous lithium hydroxide as the electrolyte showed reversible lithium intercalation. © 2020 Springer Nature Switzerland AG.|
|Gov't Doc #:||9664|
|Appears in Collections:||Journal Articles|
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.